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Thermal Studies of the Hardening of the Systems Calcium Silicates–Electrolyte–Water

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Abstract

Thermal studies, sometimes together with X-ray analysis, were applied to investigate the process of hydration in the systems calcium silicates (tricalcium silicate or dicalcium silicate) - water - electrolyte. Alkali metal or alkaline-earth metal salts were used as electrolytes. Results and conclusions are presented concerning the action of electrolytes upon the kinetics of hardening of the calcium silicates and the composition and phase transformation of calcium hydrosilicate in the presence of low proportions of electrolytes (0.5, 2 and 5 mass%), these effects being due to ionic substitution. A higher proportion of electrolyte (above 2%) in the systems calcium silicate-water can determine the formation of a complex salt, e.g. calcium hydroxysalts or double hydrosilicates.

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REFERENCES

  1. W. Richartz, Zement Kalk Gips, 22 (1969) 447.

    Google Scholar 

  2. V. S. Ramachandran, RILEM. Mat. Constr. Materials Struct., 4 (1971) 3.

    CAS  Google Scholar 

  3. M. Muntean, ‘The hardening process in the binder—electrolyte—water systems’, Thesis, Polytechnic Institute Bucharest 1972, p. 27.

  4. I. Teoreanu and M. Muntean, Silicat Ind., 39 (1974) 49.

    CAS  Google Scholar 

  5. I. Teoreanu and M. Muntean, Proced. VIth Intern. Congr. Chem. Cem., Moscow, 1974, p. 51.

  6. V. S. Ramachandran and Z. Chung-Mei, Il Cemento, 83 (1986) 129.

    Google Scholar 

  7. L. Montanaro, A. Negro and M. Regourd, Cem. Concr. Res., 18 (1988) 431.

    Article  CAS  Google Scholar 

  8. I. Teoreanu and M. Muntean, Mat. Const. (Romania), 20 (1990) 101.

    CAS  Google Scholar 

  9. H. F. W. Taylor, ‘Chemistry of Cements’, Academic Press, London 1990.

    Google Scholar 

  10. V. S. Ramachandran, J. J. Beaudoin, S. L. Sarkar and Xu Almin, Il Cemento, 90 (1993) 73.

    CAS  Google Scholar 

  11. A. Tagnit and S. Bouraaoui, Proceed. Xth Intern. Congr. Chem. Cem., Goyheburg-Sweden, Vol. 2 (1997) p. 8.

    Google Scholar 

  12. L. Chen, L. Schzong and W. Yanrong, Proceed. IVth Beijing Intern. Symp. Cem. and Concr., Intern. Acad. Publishers Vol. 1, (1998) p. 307.

    Google Scholar 

  13. S. Tsivilis, G. Kakali, E. Chaniotakis and A. Souvaridou, J. Therm. Anal. Cal., 52 (1998) 863.

    Article  CAS  Google Scholar 

  14. S. Monosi, I. Alvera and M. Collepardi, Il Cemento, 86 (1989) 97.

    Google Scholar 

  15. I. Teoreanu, M. Georgescu and G. Scaunasu, Rev. Roum. Chim., 16 (1971) 861.

    CAS  Google Scholar 

  16. Joint Comm. Diffr. Stand., Powder Diffraction., File Inorganic Phases Sets 1–5 Swarthmore, PA, USA 1974, p. 207.

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Teoreanu, I., Muntean, M. Thermal Studies of the Hardening of the Systems Calcium Silicates–Electrolyte–Water. Journal of Thermal Analysis and Calorimetry 62, 809–819 (2000). https://doi.org/10.1023/A:1026741913366

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  • DOI: https://doi.org/10.1023/A:1026741913366

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