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94-K Superconducting Yttrium Barium Cuprate Films Prepared by Spray Pyrolysis of Methacrylate Solutions

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Abstract

High-T c YBa2Cu3O7 films 2–6 μm in thickness were deposited onto lanthanum aluminate substrates by spray pyrolysis of methacrylate solutions, and their properties were studied. By optimizing the deposition conditions (substrate material, solution concentration, and firing schedule), single-phase, nearly stoichiometric films well adherent to the substrate were obtained, with T c = 94 K and ΔT = 9 K.

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REFERENCES

  1. Silver, A.H., Superconductivity in Electronics, IEEE Trans. Appl. Supercond., 1997, vol. 8, no. 2, pp. 69–79.

    Google Scholar 

  2. Perrin, C., Guilloux-Viry, M., Casiel, X., and Paven-Thivet, C., Growth and Characterization of HTSC Thin Films for Microelectronic Devices, Microelectron. J., 1996, vol. 27, no. 4/5, pp. 343–360.

    Google Scholar 

  3. Jergel, M., Synthesis of High-T c Superconducting Films by Deposition from Anaerosol, Supercond. Sci. Technol., 1995, vol. 8, pp. 67–78.

    Google Scholar 

  4. Nobumasa, H., Shimizu, K., Kitano, Y., et al., Formation of 100 K Superconducting Bi(Pb)-Sr-Ca-Cu-O Film by a Spray Pyrolysis, Jpn. J. Appl. Phys., 1988, vol. 27, no. 9, pp. 1969–1971.

    Google Scholar 

  5. Vaslow, D.F., Deikman, G.H., and Dawson, D., Superconducting Bi-Ca-Sr-Cu Oxide Films by Spray Pyrolysis of Metal Acetates, Appl. Phys. Lett., 1988, vol. 54, no. 4, pp. 324–326.

    Google Scholar 

  6. Turevskaya, E.P., Turova, N.L., Kisseler, V.G., et al., Preparation of Bi-Based High-T c Superconducting Films by Alkoxide Processing, Sverkhprovodimost: Fiz., Khim., Tekh., 1990, vol. 3, no. 9, pp. 2101–2107.

    Google Scholar 

  7. Manabe, T., Tsunoda, T., Kondo, W., et al., Preparation of Superconducting Bi(Pb)-Sr-Ca-Cu-O Films by the Dipping Pyrolysis Process, Jpn. J. Appl. Phys., 1992, vol. 31, pp. 1020–1025.

    Google Scholar 

  8. Gross, M.E., Hong, M., Liou, S.H., et al., Versatile New Metalorganic Process for Preparing Superconducting Thin Films, Appl. Phys. Lett., 1988, vol. 52, no. 2, pp. 160–162.

    Google Scholar 

  9. Klee, M., DeVries, J.W.C., and Brand, W., Superconductivity above 100 K in Bi(Pb)-Sr-Ca-Cu-O Films by Thermal Decomposition of Metal Carboxylates, Physica C (Amsterdam), 1988, vol. 156, no. 4, p. 641.

    Google Scholar 

  10. Pisarevskii, A.P., Martynenko, L.I., and Dzyubchenko, N.G., Bismuth Carboxylates, Zh. Neorg. Khim., 1990, vol. 35, no. 6, pp. 1483–1485.

    Google Scholar 

  11. Kumagai, T., Yokoba, H., Kawaguchi, K., et al., Preparation of Superconducting YBa2Cu3O7-δ Thin Films by the Dipping Pyrolysis Process Using Organic Acid Salts, Chem. Lett., 1987, pp. 1645–1646.

  12. Gross, M.E., Brown, W.L., Di Cenzo, S.B., et al., Ion Beam Patterning of Spin-on Metalorganic Precursors and Formation of High T c Superconductors, Appl. Phys. Lett., 1988, vol. 53, no. 9, pp. 802–804.

    Google Scholar 

  13. Hung, L.S., Lee, S.T., Brownstain, G.H., and Agstinelly, J.A., Epitaxially Oriented YBa2Cu3O7-x Thin Films on 〈100〉 MgO Prepared by Metallo-Organic Decomposition, J. Appl. Phys., 1989, vol. 66, no. 1, pp. 463–466.

    Google Scholar 

  14. Starostina, T.A., Syutkina, O.P., Rybakova, L.F., et al., Preparation of Yttrium Barium Cuprate Powders and Films by the Carboxylate Route, Zh. Neorg. Khim., 1992, vol. 11, pp. 2402–2405.

    Google Scholar 

  15. Adrianova, T.N., Zakharov, A.A., and Khol'kin, A.I., High-T c Films from Organic Solutions, Elektron. Prom-st., 1996, no. 2, pp. 44–75.

  16. Grishin, A.M., Yamazato, M., Yamagata, Y., and Ebihara, K., Structure and Polarization in Epitaxial Ferroelectric PbZr0.52Ti0.48O3/YBa2Cu3O7-x /Nd:YAlO3 Thin Films, Appl. Phys. Lett., 1998, vol. 72, pp. 620–622.

    Google Scholar 

  17. Phillips, J.M., Substrate Selection for High Temperature Superconducting Thin Films, J. Appl. Phys., 1996, vol. 79, no. 4, pp. 1829–1848.

    Google Scholar 

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Tomashpol'skii, Y.Y., Rybakova, L.F., Fedoseeva, O.V. et al. 94-K Superconducting Yttrium Barium Cuprate Films Prepared by Spray Pyrolysis of Methacrylate Solutions. Inorganic Materials 37, 65–70 (2001). https://doi.org/10.1023/A:1026741512112

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