Abstract
The oxidation of composite powders and monolithic AlN ― SiC, AlN ― SiC ― TiB2, and AlN ― SiC ― ZrB2 ceramics in air up to 1600°C was studied by the methods of thermogravimetric, differential thermal, x-ray diffraction, and electron-probe microanalysis. The exceptionally high corrosion resistance of these materials was established. The corrosion resistance and possibility of using structural ceramics of the systems TiB2 ― AlN, TiB2 ― TiN, and TiC0.5N0.5 in sea water was demonstrated. The toxicity of Si3N4, AlN, BN, and TiN powders was analyzed on the basis of their reactions with biochemical media. It was proven that TiN based materials are highly stable in the oral cavity.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
I. N. Frantsevich, R. F. Voitovich, and V. A. Lavrenko, High-Temperature Oxidation of Metals and Alloys [in Russian], Gostekhizdat USSR, Kiev (1963).
V. A. Lavrenko and V. L. Tikush, Chemical Reaction of Materials with Rarefied Gases [in Russian], Nauk. Dumka, Kiev (1992).
V. A. Lavrenko and Yu. G. Gogotsi, Corrosion of Structural Ceramics [in Russian], Metallurgiya, Moscow (1989).
Yu. G. Gogotsi and V. A. Lavrenko, Corrosion of High Performance Ceramics, Springer-Verlag, Berlin, Heidelberg (1992).
Yu. G. Gogotsi, J. Desmaison, R. A. Andrievski, et al., “AlN-based ceramics-an alternative to Si3N4 and SiC in high-temperature applications,” Key Eng. Mat., 132-136, No. 3, 1600-1603 (1997).
V. A. Lavrenko, M. Desmaison-Brut, A. D. Panasyuk, and J. Desmaison, “Features of corrosion resistance of AlN-SiC ceramics in air up to 1600°C,” J. Europ. Ceram. Soc., 18, 2339-2343 (1998).
V. A. Lavrenko, J. Desmaison, A. D. Panasyuk, et al., “Corrosion-resistant composites in the AlN-SiC system with TiB2 additives,” in: Proc. 6th Conf. Europ. Ceramic Soc., Brighton (1999), Vol. 1, pp. 445-446.
V. A. Lavrenko, J. Desmaison, A. D. Panasyuk, et al., “High-temperature oxidation of AlN-SiC-ZrB2 composite ceramics,” in: Proc. 9th Cimtec-World Ceramics Congress, Florence (1999), A, pp. 417-421.
V. A. Lavrenko, A. P. Pomitkin, and Ye. S. Lugovskaya, “High-temperature oxidation of silicon carbide in oxygen discharge,” J. Oxidation of Metals, No. 2, 97-100 (1976).
J. A. Costello and R. E. Tressler, “Oxidation kinetics of hot-pressed and sintered SiC,” J. Amer. Ceram. Soc., 64, 327-331 (1981).
A. H. Heuer, L. U. Ogbuji, and T. E. Mitchell, “Microstructure of oxide scales on oxidized Si and SiC single crystals,” J. Amer. Ceram. Soc., 63, 354-355 (1980).
V. A. Lavrenko and A. F. Alexeev, “Oxidation of sintered aluminum nitride,” Ceram. Int., 9, 80-82 (1983).
A. D. Katnani and K. I. Papathomaz, “Kinetics and initial stages of oxidation of aluminum nitride: thermogravimetric analysis and x-ray photo-electron spectroscopy study,” J. Vac. Sci. Technol., A5, 1335-1340 (1987).
D. Suryanarayana, “Oxidation kinetics of aluminum nitride,” J. Amer. Ceram. Soc., 73, 1108-1110 (1990).
S. V. Schneider, M. Desmaison-Brut, Yu. G. Gogotsi, and J. Desmaison, “Oxidation behavior of hot isostatically pressed AlN -TiB2 composite,” Key Eng. Mat., 113, 49-58 (1996).
V. A. Lavrenko, L. A. Glebov, and E. S. Lugovskaya, “High-temperature oxidation of zirconium boride in oxygen,” Zh. Fiz. Khim., 47, No. 4, 887-890 (1973).
V. A. Lavrenko, V. A. Shvets, M. Desmaison-Brut, et al., “Kinetics of electrochemical processes on the surface of TiB2-AlN, TiB2-TiN, and TiC0.5N0.5 ceramics in 3% NaCl solution,” in: Abstr. Int. Conf. Advanced Materials, Kiev, 1999, p. 137.
B. I. Nabivanets, E. N. Knyaseva, E. P. Klimenko, and L. N. Dovgan', “Method for determining the concentration of titanium in a solution,” Zh. Anal. Khim, 37, No. 2, 247-250 (1982).
V. A. Lavrenko, E. V. Lysenko, E. N. Knyaseva, et al., “Features of the anodic behavior of titanium carbide in sulfuric acid,” Dokl. Akad. Nauk. SSSR, 267, No. 6, 1395-1398 (1982).
A. M. Shevchenko, G. A. Shkurko, O. V. Zadorina, and N. V. Boshitskaya, “Toxic and fibrogenic action of silicon nitride obtained by a plasmochemical method,” Poroshk. Metall., Nos. 1-2, 117-118 (1994).
N. V. Boshitskaya, T. S. Bartnitskaya, V. A. Lavrenko, and G. N. Makarenko, “Interaction of Si3N4 nanopowders with biochemical media,” in: Proc. 8th Conf. Europ. Ceram. Soc., Brighton, 1999, Vol. 2, pp. 235-236.
T. S. Bartnitskaya, N. V. Boshitskaya, V. A. Lavrenko, et al., “Reaction of silicon nitride powder with media of the living organism,” Ukr. Khim. Zh., 63, Nos. 1-2, 16-19 (1997).
N. V. Boshitskaya, V. A. Lavrenko, T. S. Bartnitskaya, et al., “Reaction of aluminum nitride powder with biochemical media,” Poroshk. Metall., Nos. 3-4, 53-61 (2000).
N. G. Kakazei, V. A. Lavrenko, N. V. Boshitskaya, and G. A. Shkurko, “Reaction of boron nitride powder with biochemical media,” Poroshk. Metall., Nos. 1-2, 82-88 (2000).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lavrenko, V.A. Reaction of Composite Ceramic Materials with Corrosionally Active Media. Powder Metallurgy and Metal Ceramics 39, 369–380 (2000). https://doi.org/10.1023/A:1026665523478
Issue Date:
DOI: https://doi.org/10.1023/A:1026665523478