Abstract
Analysis of experimental data suggests that the ratio of the concentrations of uncomplexed Pb and Cd ions in the reaction system can be used to predict the composition of Cd x Pb1 – x S films deposited from aqueous solutions. To this end, the appropriate best fit equations are derived from experimental data.
Similar content being viewed by others
REFERENCES
Kepi, W. and Zemel, J.N., Properties of CdxPb1 - x S Epitaxial Films, J. Vac. Sci. Technol., 1969, vol. 6, no. 4, pp. 494–501.
Behtke, P.M. and Barton, P.B., Subsolidus Relations in the System PbS-CdS, Am. Miner., 1971, vol. 56, p. 2034.
Calawa, A.R., Mroczkowski, J.A., and Harman, T.C., Preparation and Properties of PbxCd1 - x S, J.Electron. Mater., 1972, vol. 1, pp. 191–201.
Ugai, Ya.A., Yatsenko, E.B., and Averbakh, E.M., Optical Properties of Chemically Deposited PbS and CdS Films, Tverdotel'naya radioelektronika (Solid-State Electronics), Voronezh: Voronezh. Gos. Univ., 1973, pp. 77–81.
Strel'tsov, E.A., Osipovich, N.P., Ivashkevich, L.S., and Lyakhov, A.S., Electrochemical Texturing of Solutions, Zh. Prikl. Khim. (S.-Peterburg), 1998, vol. 71, no. 10, pp. 1651–1653.
Vesnin, Yu.I., On the Mechanism of Formation of Substitutional Solid Solutions, Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk, 1985, vol. 15, no. 5, pp. 7–10.
Kitaev, G.A. et al., On the Preparation of Mixed Metal Chalcogenides by Chemical Means, in Khimiya i fizika khal'kogenidov (Chemistry and Physics of Chalcogenides), Kiev: Naukova Dumka, 1977, pp. 107–110.
Kitaev, G.A., Markov, V.F., Maskaeva, L.N., et al., Synthesis and Properties of CdxPb1 - x S Films, Izv. Akad. Nauk SSSR, Neorg. Mater., 1990, vol. 26, no. 2, pp. 248–250.
Mukhamed'yarov, R.D., Kitaev, G.A., Markova, V.M., and Stuk, V.I., Growth Kinetics of Polycrystalline CdxPb1 - x S Films during Chemical Deposition from Aqueous Solutions, Izv. Akad. Nauk SSSR, Neorg. Mater., 1981, vol. 17, no. 10, pp. 1739–1741.
Kitaev, G.A., Markov, V.F., and Maskaeva, L.N., Conditions for the Formation of Polycrystalline Films of II-VI, IV-VI, and Their Solid Solutions, in Fizika kristallizatsii (Physics of Crystallization), Tver: Tversk. Gos. Univ., 1994, pp. 29–38.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Markov, V.F., Maskaeva, L.N. & Kitaev, G.A. Predicting the Composition of CdxPb1 – xS Films Deposited from Aqueous Solutions. Inorganic Materials 36, 1194–1196 (2000). https://doi.org/10.1023/A:1026613127267
Issue Date:
DOI: https://doi.org/10.1023/A:1026613127267