Abstract
A fugacity-based model to explain the partitioning of contaminants in the environment is evaluated. Using emission inventories, air and water concentrations predicted by the model for the southwestern Québec region generally agree with field data for phenanthrene, α-HCH, lindane, and DDT. For pyrene, air concentrations are in agreement but water concentrations were in error by a factor of nearly 20. There is also a possibility for using the model to predict emissions from known air and water concentrations. The model was run over 120 times each for phenanthrene, HCB, and lindane while randomly varying the input parameters each time. A Principal Components Analysis and a partial correlation analysis indicate that certain input parameters are more important for some compounds than for others and that log Kow is the physical-chemical property of greatest importance.
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Baker, J. E. and Eisenreich, S. J.: 1990, Environ. Sci. Technol. 24, 342.
Ballschmiter, K. and Wittlinger, R.: 1991, Environ. Sci. Technol. 25, 1103.
Barrie, L. A., Gregor, D., Hargrave, B., Lake, R., Muir, D., Shearer, R., Tracey, B. and Bidleman, T.: 1992, The Science of the Total Environment 122, 1.
Brun, G. L., Howell, G. D. and O'Neill, H. J.: 1991, Environ. Sci. Technol. 25, 1249.
Cohen, Y., Tsai, W., Chetty, S. L. and Mayer, G. J.: 1990, Environ. Sci. Technol. 24, 1549.
Comba, M. E., Palabrica, V. S., Wasslen, J. and Kaiser, K. L. E.: 1987, St. Lawrence trace organic contaminants study (part III), 1987. National Water Research Institute (NWRI) contribution no. 90-01.
Cowan, C. E., Mackay, D., Feijtel, T. C. J., Van de Meent, D., Di Guardo, A., Davies, J. and Mackay, N.: 1995, The Multi-media Fate Model: A Vital Tool for Predicting the Fate of Chemicals, SETAC Press, p. 78.
EPA (US Environmental Protection Agency): 1989, Chemical fate rate constants for SARA section 313 chemicals and Superfund health evaluation manual chemicals. Office of Toxic Substances, EPA 68-02-4254, Washington, DC.
Germain, A. and Langlois, C.: 1988, Water Pollut. Res. J. Can. 23, 602.
Hoff, R. M., Muir, D. C. G. and Grift, N. P.: 1992, Environ. Sci. Technol. 26, 266.
HWC and EC (Health and Welfare Canada and Environment Canada): 1993, Hexachlorobenzene: Priority substance list assessment report. Canadian Environmental Protection Act (CEPA).
Johnson, R. A. and Wichern, D. W.: 1982, Applied Multivariate Statistical Analysis, New Jersey: Prentice-Hall.
Jolliffe, I. T.: 1986, Principal component analysis, 271 p., Springer, Berlin.
Lane, D. A., Johnson, N. D., Hanley, M.-J., Schroeder, W. H. and Ord, D. T.: 1992, Environ. Sci. Technol. 26, 126.
Langlois, C. and Sloterdijk, H.: 1989, Revue des Sciences de l'Eau 2, 659.
Lavalin Environnement: 1988, Inventaire des sources d'hydrocarbures aromatiques polycycliques au Québec. Rapport final. Environnement Canada, Conservation et Protection, Dossier no. 55526.
Legendre, L. and Legendre, P.: 1984, écologie numérique. Edition Masson, p. 260.
Mackay, D. and Paterson, S.: 1990, in: W. Karcher and J. Devillers (eds.), Practical Applications of Quantitative Structure-activity Relationships (QSAR) in Environmental Chemistry and Toxicology, ECSC, EEC, EAEC, Brussels and Luxembourg, p. 433.
Mackay, D., Paterson, S. and Tam, D. D.: 1991, Assessments of Chemical fate in Canada: Continued development of a fugacity model. A report prepared for Health and Welfare Canada.
Mackay, D., Paterson, S. and Shiu, W. Y.: 1992, Chemosphere 24, 695.
Malaiyandi, M. and Shah, S. M.: 1984, J. Environ. Sci. Health, A19(8), 887.
McKone, T. E. and Layton, D. W.: 1986, Reg. Toxicol. Pharmacol. 6, 359.
Oehme, M. and Mano, S.: 1984, Fres. Z. Anal. Chem. 319, 141.
Oliver, B. G. and Niimi, A. J.: 1988, Environ. Sci. Technol. 22, 388.
Pham, T., Lum, K. and Lemieux, C.: 1993, Chemosphere 27, 1137.
Poissant, L., Koprivnjak, J. F., Besner, M., Tremblay, J. and Lum, K.: 1994, Compte Rendu du 6e colloque sur les substances toxiques (Proceedings of the 6th conference on toxic substances), Montreal, 10 et 11 mai 1994, p. 257.
Poissant, L. and Koprivnjak, J. F.: 1995, Reference guide for organic and inorganic airborne toxic contaminants. Unpublished m.s.
Poissant, L. and Koprivnjak, J. F.: 1996, Environ. Sci. Technol. 30(3), 845-851.
Richman, M. B.: 1986, J. Climatol. 6, 293-335.
Rondeau, B.: 1993, Qualité des eaux du fleuve Saint-Laurent 1985–1990. Troncon Cornwall-Québec. Centre Saint-Laurent, Environnement Canada.
Suntio, L. R., Shiu, W. Y., Mackay, D., Seiber, J. N. and Glotfelty, D.: 1988, Reviews of Environmental Contamination and Toxicology 103, 1.
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Koprivnjak, JF., Poissant, L. EVALUATION AND APPLICATION OF A FUGACITY MODEL TO EXPLAIN THE PARTITIONING OF CONTAMINANTS IN THE ST. LAWRENCE RIVER VALLEY. Water, Air, & Soil Pollution 97, 379–395 (1997). https://doi.org/10.1023/A:1026496527596
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DOI: https://doi.org/10.1023/A:1026496527596