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Growth Mechanism of Large Monodispersed Silica Particles Prepared from Tetraethoxysilane in the Presence of Sodium Dodecyl Sulfate

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Abstract

Monodispersed silica particles up to ca. 1.2 μm in diameter were prepared by hydrolysis of tetraethoxysilane in the presence of sodium dodecyl sulfate (SDS). The particle size was increased with an increase of SDS added. The geometrical standard deviation of the particles was decreased with an increase of SDS. In the earlier reaction stage, double spherical particles by the coalescence of the particles were frequently observed when large amounts of SDS were added. Particle size was gradually increased after the coalescence occurred and spherical particles were finally obtained. The results of Nielsen's chronomal analysis suggest that the polynuclear layer growth took place after the coalescence of the particles in the presence of larger amount of SDS.

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Authors and Affiliations

  1. Department of Applied Materials Science, College of Engineering, Osaka Prefecture University, Sakai, Osaka, 593, Japan

    Hideki Nishimori, Masahiro Tatsumisago & Tsutomu Minami

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  1. Hideki Nishimori
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  2. Masahiro Tatsumisago
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  3. Tsutomu Minami
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Nishimori, H., Tatsumisago, M. & Minami, T. Growth Mechanism of Large Monodispersed Silica Particles Prepared from Tetraethoxysilane in the Presence of Sodium Dodecyl Sulfate. Journal of Sol-Gel Science and Technology 9, 25–31 (1997). https://doi.org/10.1023/A:1026404105736

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  • DOI: https://doi.org/10.1023/A:1026404105736

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