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Densities, Viscosities, Sound Speeds, and Excess Properties of Binary Mixtures of Methyl Methacrylate with Alkoxyethanols and 1-Alcohols at 298.15 and 308.15 K

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Abstract

The densities, viscosities, and sound speeds were measured for six binary mixtures of methyl methacrylate (MMA)+2-methoxyethanol (ME), +2-ethoxyethanol (EE), +2-butoxyethanol (BE), +1-butanol (1-BuOH), +1-pentanol (1-PeOH), and +1-heptanol (1-HtOH) at 298.15 and 308.15 K. The mixture viscosities were correlated by Grunberg–Nissan, McAllister, and Auslander equations. The sound speeds were predicted by using free length and collision factor theoretical formulations, and Junjie and Nomoto equations. The excess viscosities and excess isentropic compressibilities were also calculated. A qualitative analysis of both of these functions revealed that structure disruptions are more predominant in MMA+1-alcohol than in MMA+alkoxyethanols mixtures. The estimated relative associations are found to become less in MMA+alcohol mixtures than in pure alcohols. The solvation numbers derived from the isentropic compressibility of the mixtures, considering MMA as a solvent, showed that structure making interactions are also present in MMA + alkoxyethanols in addition to the structure disruptions.

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REFERENCES

  1. T. Truruta, T. Makimoto, and H. Kanai, J. Macromol. Sci. Chem. A 12:1513 (1978).

    Google Scholar 

  2. N. Hadjichristidis and L. J. Fetters, Macromolecules 17:2303 (1984).

    Google Scholar 

  3. T. Ishikawa and B. C.-Y. Lu, J. Chem. Thermodyn. 3:23 (1979).

    Google Scholar 

  4. J.-M. Yu, T. Ishikawa, and B. C.-Y. Lu, J. Chem. Thermodyn. 12:57 (1980).

    Google Scholar 

  5. D. Lhang, G. C. Benson, M. K. Kumaran, and B. C.-Y. Lu, J. Chem. Thermodyn. 18:149 (1986).

    Google Scholar 

  6. W. R. Liau, M. Tang, and Y.-P. Chen, J. Chem. Eng. Data 43:826 (1998).

    Google Scholar 

  7. N. V. Sastry and M. K. Valand, Phys. Chem. Liq. 38:61 (2000).

    Google Scholar 

  8. N. V. Sastry and M. K. Valand, Ber. Bunsenges. Phys. Chem. 102:686 (1998).

    Google Scholar 

  9. N. V. Sastry and M. K. Valand, Int. J. Thermophys. 18:1387 (1997).

    Google Scholar 

  10. N. V. Sastry, M. K. Valand, John George, and S. R. Patel, submitted to J. Chem. Eng. Data (in press).

  11. L. Grunberg and A. H. Nissan, Trans. Faraday Soc. 45:125 (1949).

    Google Scholar 

  12. R. A. McAllister, AIChE J. 6:427 (1960).

    Google Scholar 

  13. G. Auslander, Br. Chem. Eng. 9:610 (1964).

    Google Scholar 

  14. B. Jacobson, Acta Chem. Scand. 8:1485 (1952).

    Google Scholar 

  15. W. von Schaaffs, Molekularakustik (Springer Verlag, Berlin, 1963), Chaps. XI and XII.

    Google Scholar 

  16. W. von Schaaffs, Z. Phys. 114:110 (1974).

    Google Scholar 

  17. Z. Junjie, J. China Univ. Sci. Technol. 14:298 (1984).

    Google Scholar 

  18. O. Nomoto, J. Phys. Soc. Jpn. 13:298 (1958).

    Google Scholar 

  19. R. L. Mishra and J. D. Pandey, Ind. J. Pure Appl. Phys. 15:505 (1977).

    Google Scholar 

  20. R. J. Fort and W. R. Moore, Trans. Faraday Soc. 62:1112 (1966).

    Google Scholar 

  21. N. V. Sastry and M. K. Valand, J. Chem. Eng. Data 41:1426 (1996).

    Google Scholar 

  22. N. V. Sastry and M. K. Valand, J. Chem. Eng. Data 43:152 (1998).

    Google Scholar 

  23. N. V. Sastry and M. M. Raj, Ind. J. Chem. A 35:49 (1996).

    Google Scholar 

  24. N. V. Sastry, S. R. Patel, J. George, and D. H. L. Prasad, submitted to Ind. J. Chem. (in press).

  25. L. S. Prabhumirashi and C. I. Jose, J. Chem. Soc. Faraday Trans. II 72:1721 (1976).

    Google Scholar 

  26. L. S. Prabhumirashi, J. Chem. Soc. Faraday Trans. II 74:1567 (1978).

    Google Scholar 

  27. J. Valero, M. Garcia, and C. Gutierrez Losa, J. Chem. Thermodyn. 11:1101 (1979).

    Google Scholar 

  28. B. Luo, S. E. M. Hamam, G. C. Benson, and B. G. Y. Lu, J. Chem. Thermodyn. 18:1043 (1986).

    Google Scholar 

  29. P. K. Muhari and D. K. Hazare, J. Chem. Eng. Data 40:582 (1995).

    Google Scholar 

  30. T. M. Aminabhavi and B. Gopalakrishna, J. Chem. Eng. Data 40:632 (1995).

    Google Scholar 

  31. J. H. MacNeil and R. Palepu, Thermochim. Acta 39:257 (1995).

    Google Scholar 

  32. TRC Thermodynamic Tables, Version 1–2 (Thermodynamic Research Center, College Station, TX, 1994)

  33. M. Diaz Pena and G. Taradajos, J. Chem. Thermodyn. 11:441 (1979).

    Google Scholar 

  34. R. C. Wilhoit and B. J. Zwolinski, J. Phys. Chem. Ref. Data II:Suppl. 1 (1973).

  35. M. A. Rauf, G. H. Stewart, and Farhataziz, J. Chem. Eng. Data 28:324 (1983).

    Google Scholar 

  36. T. A. Aminabhavi, M. E. Aralaguppi, S. B. Hargoppad, and R. H. Balandgi, J. Chem. Eng. Data 38:931 (1993).

    Google Scholar 

  37. J. A. Riddick, W. B. Bunger, and T. Sakano, in Techniques of Chemistry, Vol. II (John Wiley and Sons, New York, 1986).

    Google Scholar 

  38. G. Douheret, A. Pal, and M. I. Davis, J. Chem. Thermodyn. 22:99 (1990).

    Google Scholar 

  39. M. G. S. Rao and B. R. Rao, J. Sci. Industr. Res. B 21:331 (1962).

    Google Scholar 

  40. S. Prakash and O. Prakash, Acoustica 32:279 (1975).

    Google Scholar 

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  1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar-, 388 120, Gujarat, India

    N. V. Sastry & S. R. Patel

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  1. N. V. Sastry
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Sastry, N.V., Patel, S.R. Densities, Viscosities, Sound Speeds, and Excess Properties of Binary Mixtures of Methyl Methacrylate with Alkoxyethanols and 1-Alcohols at 298.15 and 308.15 K. International Journal of Thermophysics 21, 1153–1174 (2000). https://doi.org/10.1023/A:1026402222130

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