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Kinetics of Hydrogen Peroxide Accumulation in Electrosynthesis from Oxygen in Gas-Diffusion Electrode in Acidic and Alkaline Solutions

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Abstract

Accumulation of H2O2 in aqueous solutions with various pH values in electroreduction of oxygen in carbon-black gas-diffusion hydrophobized electrodes was studied. The effect of various parameters of the process on its electrochemical component and decomposition rate of the H2O2 formed was analyzed.

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References

  1. Vasil'eva, I.S., Kornienko, V.L., and Kolyagin, G.A., Khim. Inter. Ustoich. Razv., 2001, vol. 9, no. 4, pp. 529-532.

    Google Scholar 

  2. Pletcher, D., Acta Chem. Scand., 1999, vol. 53, p. 745.

    Google Scholar 

  3. Brillas, E., Bastida, R. M., Llosa, E., and Casado, J., J. Electrochem. Soc., 1995, vol. 142, no. 6, pp. 1733-1741.

    Google Scholar 

  4. Nagiev, T.M., Usp. Khim., 1985, vol. 54, no. 10, pp. 1654-1673.

    Google Scholar 

  5. Schumb, W.C., Satterfield, Ch.N., and Wentworth, R.L., Hydrogen Peroxide, New York: Chapman and Hall, 1955.

    Google Scholar 

  6. Khimiya i tekhnologiya perekisi vodoroda (Chemistry and Technology of Hydrogen Peroxide), Seryshev, G.A., Ed., Leningrad: Khimiya, 1984.

    Google Scholar 

  7. Kornienko, V.L., Kolyagin, G.A., and Saltykov, Yu.V., Zh. Prikl. Khim., 1999, vol. 72, no. 3, pp. 353-361.

    Google Scholar 

  8. Kolyagin, G.A. and Kornienko, V.L., Khim. Inter. Ustoich. Razv., 2000, vol. 8, no. 6, pp. 803-807.

    Google Scholar 

  9. Vert, Zh.L. and Pavlova, V.F., Zh. Prikl. Khim., 1988, vol. 61, no. 5, pp. 1148-1150.

    Google Scholar 

  10. Balej, J. and Spalek, O., Coll. Czech. Chem. Commun., 1979, vol. 44, no. 2, pp. 488-494.

    Google Scholar 

  11. Spalek, O., Balej, J., and Paseka, I., J. Chem. Soc., Faraday Trans. 1, 1982, vol. 78, pp. 2349-2359.

    Google Scholar 

  12. Duke, F.R. and Haas, T.W., J. Phys. Chem., 1961, vol. 65, no. 2, pp. 304-306.

    Google Scholar 

  13. Moiseev, I.I., Izv. Akad. Nauk, Ser. Khim., 1995, no. 3, pp. 578-588.

    Google Scholar 

  14. Gyenge, E.L. and Oloman, C.W., J. Appl. Electrochem., 2001, vol. 31, no. 2, pp. 233-243.

    Google Scholar 

  15. Chaenko, N.V., Kornienko, G.V., Vasil'eva, I.S., and Kornienko, V.L., Zh. Prikl. Khim., 1996, vol. 69, no. 5, pp. 792-794.

    Google Scholar 

  16. Kenova, T.A., Abolin, O.E., and Kornienko, V.L., Zh. Prikl. Khim., 1991, vol. 64, no. 3, pp. 792-794.

    Google Scholar 

  17. Kolyagin, G.A. and Kornienko, V.L., Zh. Prikl. Khim., 1989, vol. 62, no. 9, pp. 2082-2087.

    Google Scholar 

  18. Chaenko, N.V., Kornienko, G.V., Kenova, T.A., et al., Zh. Prikl. Khim., 2000, vol. 73, no. 1, pp. 51-54.

    Google Scholar 

  19. Kanter, M.Ya., Raskina, I.Kh., Bogdanov, G.A., and Koziv, Yu.N., Zh. Prikl. Khim., 1977, vol. 50, no. 4, pp. 724-731.

    Google Scholar 

  20. Raskina, I.Kh., Sadov, F.I., and Bogdanov, G.A., Zh. Prikl. Khim., 1977, vol. 39, no. 1, pp. 35-39.

    Google Scholar 

  21. Anurova, A.I., Daniel'-Bek, V.S., and Rotinyan, A.L., Elektrokhimiya, 1968, vol. 4, no. 7, pp. 815-821.

    Google Scholar 

  22. Malyshev, V.A. Abolin, O.E., and Kornienko, V.L., Zh. Prikl. Khim., 1991, vol. 64, no. 10, pp. 2181-2183.

    Google Scholar 

  23. Khomutov, N.E., Khachaturyan, O.B., and Khokhlov, M.I., Zh. Prikl. Khim., 1987, vol. 60, no. 1, pp. 31-34.

    Google Scholar 

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Kolyagin, G.A., Kornienko, V.L. Kinetics of Hydrogen Peroxide Accumulation in Electrosynthesis from Oxygen in Gas-Diffusion Electrode in Acidic and Alkaline Solutions. Russian Journal of Applied Chemistry 76, 1070–1075 (2003). https://doi.org/10.1023/A:1026398025991

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