Abstract
Solid-state electrochemical sensor devices combined with a sodium ion conductor (Na5DySi4O12) disc and metal-sulfide sensing electrodes synthesized via solution routes have been investigated for the detection of SO2 in the range 20–200 ppm at 150–400°C. Among the various sulfide sensing electrodes tested, the metal-mono sulfide-based electrodes (NiS, CdS, SnS and PbS) gave good SO2 sensitivity at 300–400°C. The CdS-based solid electrolyte sensor element showed the best sensing characteristics, i.e., the EMF response was almost linear with the logarithm of SO2 concentration in the range between 20 and 200 ppm, with a 90% response time to 100 ppm SO2 of about 2–4 min at 400°C.
Similar content being viewed by others
References
M. Gauthier and A. Chamberland, J. Electrochem. Soc. 124 (1977) 1579.
K. T. Jacob and D. B. Rao, ibid. 126 (1979) 1842.
M. Gauthier, R. Bellemare and A. Belanger, ibid. 128 (1981) 371.
Q. G. Liu and W. L. Worrell, Solid State Ion. 18/19 (1986) 524.
W. L. Worrell, in “Chemical Sensor Technology,” edited by T. Seiyama (Kodansha/Elsevier, Tokyo, 1988) p. 97.
N. Imanaka, Y. Yamaguchi, G. Adachi and J. Shiokawa, Bull. Chem. Soc. Jpn. 58 (1985) 5.
Y. Saito, T. Maruyama, Y. Matsumoto, K. Kobayashi and Y. Yano, Solid State Ion. 14 (1984) 273.
N. Imanaka, Y. Yamaguchi, G. Adachi, J. Shiokawa and H. Yoshioka, ibid. 20 (1986) 153.
Y. Shimizu, N. Matsunaga, T. Hyodo and M. Egashira, Sensors and Actuators B 77 (2001) 35.
C.-Y. Chiou and T.-C. Chou, ibid. 87 (2002) 1.
K. H. Karmarkar and G. G. Guilbault, Anal. Chim. Acta 71 (1974) 419.
W. Weppner, Sensors and Actuators 12 (1987) 107.
N. Yamazoe, Chem. Sens. 8 (1992) 8.
Y. Shimizu, Denki Kagaku (Presently Electrochemistry) 63 (1995) 794.
R. Akila and K. T. Jacob, Sensors and Actuators 16 (1989) 311.
K. T. Jacob, M. Iwase and Y. Waseda, Solid State Ion. 23 (1987) 245.
G. Rog, A. Kozlowska-Rog, K. Zakula, W. Bogusz and W. Pycior, J. Appl. Electrochem. 21 (1991) 308.
S. Zhuiykov, Fuel 79 (2000) 1255.
Y. Yan, Y. Shimizu, N. Miura and N. Yamazoe, Chem. Lett. (1992) 635.
Y. Yan, N. Miura and N. Yamazoe, J. Electrochem. Soc. 143 (1996) 609.
T. Maruyama, Y. Saito, Y. Matsumoto and Y. Yano, Solid State Ion. 17 (1985) 281.
R. Akila and K. T. Jacob, J. Appl. Electrochem. 18 (1988) 245.
D. J. Slater, R. V. Kumar and D. J. Fray, Solid State Ion. 86–88 (1996) 1063.
L. Wang and R. V. Kumar, J. Electroanal. Chem. 543 (2003) 109.
M. Taniguchi, M. Wakihara, T. Uchida, K. Hirakawa and J. Nii, J. Electrochem. Soc. 135 (1988) 217.
J. Kirchnerova, C. W. Bale and J. M. Skeaff, Solid State Ion. 91 (1996) 257.
N. Souda and Y. Shimizu, in Proc. of the 5th East Asian Conference on Chemical Sensors, Nagasaki, Japan (2001) p. 179.
J. Grau and M. Akinc, J. Amer. Ceram. Soc. 80 (1997) 941.
Y. Shimizu, T. Yano, H. Suzuki, S. Kouno and T. Izumi, Electrochim. Acta., submitted.
Y. Shimizu and T. Yano, Chem. Lett. (2001) 1028.
Y. Shimizu, Y. Azuma and S. Michishita, J. Mater. Chem. 7 (1997) 1487.
R. D. Shannon, B. E. Taylor, T. E. Gier, H.-Y. Chen and T. Berzins, Inorg. Chem. 17 (1978) 958.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Souda, N., Shimizu, Y. Sensing properties of solid electrolyte SO2 sensor using metal-sulfide electrode. Journal of Materials Science 38, 4301–4305 (2003). https://doi.org/10.1023/A:1026378931023
Issue Date:
DOI: https://doi.org/10.1023/A:1026378931023