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Polarization of the Fluorescence Excited in the P- and R Branches of the Vibronic Lines of Jet-Cooled Complex Molecules

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Journal of Applied Spectroscopy Aims and scope

Abstract

A model is suggested to calculate the degree of polarization of the fluorescence of jet-cooled polyatomic molecules excited within the P- and R branches of the rotational contour of the vibronic line by light not providing resolution of the rotational structure. These dependences are calculated and compared with experimental data for molecules belonging to different types of asymmetric tops with different intramolecular orientation of the fluorescence transition dipole moment: anthracene; anthracene + Ar; 1,4-diaminoanthraquinone; indole; tetracene, and triphendioxazine.

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REFERENCES

  1. N. A. Borisevich, V. A. Tolkachev, A. P. Blokhin, and V. A. Povedailo, Vestsi Nats. Akad. Navuk Belarusi, Ser. Fiz.-Mat. Navuk, No. 4, 57-64 (1998).

    Google Scholar 

  2. V. A. Tolkachev, Zh. Prikl. Spektrosk., 65, 843-849 (1998).

    Google Scholar 

  3. V. A. Tolkachev, Zh. Prikl. Spektrosk., 66, 758-764 (1999).

    Google Scholar 

  4. V. A. Tolkachev, Zh. Prikl. Spektrosk., 69, 617-621 (2002).

    Google Scholar 

  5. Yu. A. Sadov, Prikl. Mat. Mekh., No. 5, 962-963 (1970).

    Google Scholar 

  6. S. D. Augustin and H. Rabitz, J. Chem. Phys., 71, 4956-4967 (1979).

    Google Scholar 

  7. V. M. Strel'chenya, Vestn. LGU, No. 7, 105-108 (1983).

    Google Scholar 

  8. V. A. Tolkachev and S. A. Polubisok, Opt. Spektrosk., 84, 928-934 (1998).

    Google Scholar 

  9. G. M. Nathanson and G. M. McClelland, J. Chem. Phys., 81, 629-642 (1984).

    Google Scholar 

  10. N. Ohta, O. Sekiguchi, and H. Baba, J. Chem. Phys., 82, 1609-1610 (1985); Chem. Phys. Lett., 126, 583-587 (1986).

    Google Scholar 

  11. P.-N. Wang and E. C. Lim, Chem. Phys. Lett., 142, 389-392 (1987).

    Google Scholar 

  12. V. A. Povedailo, S. A. Polubisok, and V. A. Tolkachev, Opt. Spektrosk., 80, 70-74 (1996).

    Google Scholar 

  13. N. A. Borisevich, S. L. Dzerzhitskii, V. A. Povedailo, and V. A. Tolkachev, Zh. Prikl. Spektrosk., 69, 493-796 (2002).

    Google Scholar 

  14. V. A. Tolkachev, Dokl. Nats. Akad. Nauk Belarusi, 42, 50-55 (1998).

    Google Scholar 

  15. V. A. Tolkachev, Zh. Prikl. Spektrosk., 66, 758-764 (1999).

    Google Scholar 

  16. A. P. Blokhin, Vestsi Akad. Navuk BSSR, Ser. Fiz.-Mat. Navuk, No. 2, 70-79 (1986).

    Google Scholar 

  17. V. A. Tolkachev and S. A. Polubisok, Spectrosc. Lett., 28, No. 3, 441-450 (1995).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70 F. Skorina Ave., Minsk, 220072, Belarus

    V. A. Tolkachev

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  1. V. A. Tolkachev
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Tolkachev, V.A. Polarization of the Fluorescence Excited in the P- and R Branches of the Vibronic Lines of Jet-Cooled Complex Molecules. Journal of Applied Spectroscopy 70, 526–531 (2003). https://doi.org/10.1023/A:1026190212921

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  • DOI: https://doi.org/10.1023/A:1026190212921

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