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Determination of the Thermodynamic Characteristics of Complexes of Chlorosubstituted Anilines with Proton Acceptors

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Abstract

The influence of temperature on the spectral parameters of the absorption bands ν(NH) of free and hydrogen-bonded molecules of chlorosubstituted anilines with various proton acceptors in a CCl4 medium has been studied in a temperature range of 290–330 K. The temperature dependence of the monomer–complex equilibrium constants has been investigated and the thermodynamic characteristics of the complexes have been calculated.

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  1. Tyumen' State University, 10 Semakov Str., Tyumen', 625003, Russia

    A. V. Morev & A. N. Yakimov

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  1. A. V. Morev
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  2. A. N. Yakimov
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Morev, A.V., Yakimov, A.N. Determination of the Thermodynamic Characteristics of Complexes of Chlorosubstituted Anilines with Proton Acceptors. Journal of Applied Spectroscopy 70, 503–508 (2003). https://doi.org/10.1023/A:1026181911104

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