Abstract
Dynamic light scattering (DLS) has been used for the measurement of several thermophysical properties of the refrigerant mixtures R410A and R407C. Thermal diffusivity and sound speed have been obtained by light scattering from bulk fluids for both the liquid and vapor phases under saturation conditions over a temperature range from about 290 K up to the liquid-vapor critical point. By applying the method of DLS to a liquid-vapor interface, also called surface light scattering (SLS), the saturated liquid kinematic viscosity and surface tension can be determined simultaneously. These properties have been measured for R410A and R407C from about 240 to 330 K and 240 to 350 K, respectively. The results are discussed in detail in comparison with literature data and with a simple prediction method based on the mass-weighted properties of the pure components expressed as functions of the reduced temperature.
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A. P. Fröba, S. Will, and A. Leipertz, Int. J. Thermophys. 22:1349(2001).
H. Buchwald, J. Hellmann, H. König, and C. Meurer, SOLKANE Taschenbuch Kälte-und Klimatechnik, Solvay Fluor & Derivate GmbH, ed. (Hannover, 1997).
B. Chu, Laser Light Scattering (Academic Press, New York, 1991).
D. Langevin, Light Scattering by Liquid Surfaces and Complementary Techniques (Marcel Dekker, New York, 1992).
A. Leipertz and A. P. Fröba, in Diffusion in Condensed Matter, J. Kärger, P. Heitjans, and R. Haberlandt, eds. (Springer, Heidelberg), in press.
J. W. Schmidt and M. R. Moldover, J. Chem. Eng. Data 39:39(1994).
J. W. Schmidt, E. Carrillo-Nava, and M. R. Moldover, Fluid Phase Equilib. 122:187(1996).
J. Yata, M. Hori, and T. Minamiyama, Proc. 11th Jap. Symp. Thermophys. Prop. (1990), pp. 111-114.
A. P. Fröba, S. Will, and A. Leipertz, Fluid Phase Equilib. 161:337(1999).
A. P. Fröba and A. Leipertz, Int. J. Thermophys. 24:895(2003).
A. P. Fröba, Dr.-Ing. Thesis, Friedrich-Alexander-Universität Erlangen-Nürnberg, Erlangen (2002).
K. Kraft and A. Leipertz, Fluid Phase Equilib. 125:245(1996).
K. Kraft and A. Leipertz, Int. J. Thermophys. 15:387(1994).
K. Kraft and A. Leipertz, Proc. Int. Conf. CFCs, The Day After (Padova, 1994), pp. 435-442.
K. Kraft, Dr.-Ing. Thesis, Friedrich-Alexander-Universität Erlangen-Nürnberg, Erlangen (1995).
R. Tillner-Roth and H. D. Baehr, J. Phys. Chem. Ref. Data 23:657(1994).
S. L. Outcalt and M. O. McLinden, Int. J. Thermophys. 16:79(1995).
R. H. Perry, Chemical Engineers' Handbook (McGraw–Hill, New York, 1973).
Standard Reference Database 14, Version 4, Nat. Inst. Stds. Tech. (NIST), Boulder, Colorado (2000).
SOLKANE Refrigerant Software, Version 2.0, SOLVAY Fluor & Derivate GmbH, Hannover (1999).
N. Hoffmann, K. Spindler, and E. Hahne, in Bestimmung der Transportgrößen von HFKW, Bericht zum AiF-Forschungsvorhaben Nr. 10044B, Heft 2: Wärmeleitfähigkeit, Forschungsrat Kältetechnik e.V., ed. (Frankfurt am Main, 1996).
D. Günther and D. Steimle, in Bestimmung der Transportgrößen von HFKW, Bericht zum AiF-Forschungsvorhaben Nr. 10044B, Heft 3: Spezifische Wärmekapazität, Forschungs-rat Kältetechnik e.V., ed. (Frankfurt am Main, 1996).
A. P. Fröba, S. Will, and A. Leipertz, Int. J. Thermophys. 21:1225(2000).
C. Miqueu, D. Broseta, J. Satherley, B. Mendiboure, J. Lachaise, and A. Graciaa, Fluid Phase Equilib. 172:169(2000).
R. Heide and J. Schenk, in Bestimmung der Transportgrößen von HFKW, Bericht zum AiF-Forschungsvorhaben Nr. 10044B, Heft 1: Viskosität und Oberflächenspannung, Forschungsrat Kältetechnik e.V., ed. (Frankfurt am Main, 1996).
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Fröba, A.P., Leipertz, A. Thermophysical Properties of the Refrigerant Mixtures R410A and R407C from Dynamic Light Scattering (DLS). International Journal of Thermophysics 24, 1185–1206 (2003). https://doi.org/10.1023/A:1026152331710
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DOI: https://doi.org/10.1023/A:1026152331710