Abstract
A synthesis and a study by method of measuring the differential capacitance on a stationary mercury drop of the adsorption of a number of cubane derivatives in a surface-inactive electrolyte are performed. It is established that the compounds studied exhibit a high surface activity. For bromine derivatives of cubane (4-bromomethoxycarbonylcubane, 4-bromohydroxymethylcubane) the formation of two-dimensional adsorption layers is discovered. Values of adsorption parameters for these compounds are evaluated with use made of the Frumkin isotherm.
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Frumkin, A.N., Fedorovich, N.V., and Stenina, E.V., Itogi Nauki Tekh., Ser.: Elektrokhim., 1978, vol. 13, p. 5.
Damaskin, B.B. and Stenina, E.V., J. Electroanal. Chem., 1993, vol. 349, p. 31.
Stenina, E.V., Elektrokhimiya, 1995, vol. 31, p. 753.
Stenina, E.V. and Sviridova, L.N., Elektrokhimiya, 1999, vol. 35, p. 611.
Stenina, E.V., Sviridova, L.N., Baturina, O.A., and Damaskin, B.B., Elektrokhimiya, 1999, vol. 35, p. 1485.
De Levie, R., Chem. Rev., 1988, vol. 88, p. 599.
Buess-Herman, C., Trends in Interfacial Electrochemistry, Silva, A.F., Ed., Dordrecht: Reidel, 1986, p. 205.
Nikitas, P., Electrochim. Acta, 1994, vol. 39, p. 2055.
Moussa, A.A., Sammour, H.M., and Ghaly, H.A., Egypt. J. Chem, 1959, vol. 2, p. 169.
Lorenz, W., Z. Electrochem., 1958, vol. 62, p. 192.
Stenina, E.V., Fedorovich, N.V., Osipov, I.V., and Yusupova, V.A., Elektrokhimiya, 1979, vol. 15, p. 374.
Vetterl, V., Biophysik, 1968, vol. 5, p. 255.
Frumkin, A.N., Fedorovich, N.V., Stenina, E.V., Petukhova, G.N., Yusupova, V.A., and Shokova, E.A., Dokl. Akad. Nauk SSSR, 1971, vol. 201, p. 1406.
Eaton, P.E. and Cole, T.W., J. Am. Chem. Soc., 1964, vol. 86, pp. 962, 3157.
Eaton, P.E., Angew. Chem., 1992, vol. 104, p. 1447.
Eremenko, L.T., Romanova, L.B., Ivanova, M.E., Eremenko, I.L., Nefedov, S.E., and Struchkov, Yu.T., Izv. Akad. Nauk, Ser.: Khim., 1994, p. 457.
Eremenko, L.T., Romanova, L.B., Ivanova, M.E., Nesterenko, V.A., Malygina, V.S., Eremeev, A.B., Lagodzinskaya, G.V., and Lodygina, V.P., Izv. Akad. Nauk, Ser.: Khim., 1998, p. 1169.
Zakharov, V.V., Bugaeva, V.P., Eremenko, L.T., Romanova, L.B., Ivanova, M.E., Eremenko, I.L., and Nefedov, S.E., Izv. Akad. Nauk, Ser.: Khim., 1998, p. 1387.
Damaskin, B.B., Petrii, O.A., and Batrakov, V.V., Adsorption of Organic Compounds on Electrodes, New York: Plenum, 1971.
Stenina, E.V., Damaskin, B.B., Fedorovich, N.V., and Yusupova, V.A., Elektrokhimiya, 1972, vol. 8, p. 1409.
Stenina, E.V., Damaskin, B.B., Dyatkina, S.L., and Fedorovich, N.V., Dokl. Akad. Nauk SSSR, 1977, vol. 236, p. 400.
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Stenina, E.V., Sviridova, L.N., Krivenko, A.G. et al. New Type of an Adsorption Layer of Organic Molecules with a Cage Structure Condensed at the Electrode/Solution Interface: The Adsorption of Cubane Derivatives on a Mercury Electrode. Russian Journal of Electrochemistry 39, 1017–1024 (2003). https://doi.org/10.1023/A:1026150815589
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DOI: https://doi.org/10.1023/A:1026150815589