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Preparation and crystal structure of tungstogallate acid H5GaW12O40

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Abstract

The heteropoly tungstogallate acid H5GaW12O40 has been synthesized and characterized. Colorless octahedral crystals of the title compound were crystallized from acetonitrile with formula H5GaW12O40. The single crystal X-ray structure analysis of the title compound revealed that it crystallized in monoclinic system, space group Cm with a = 17.691 (4) Å, b = 25.065 (5) Å, c = 15.315 (3) Å, β = 125.21 (3)°, V= 5548.5 (19) Å3, and Z = 2. The crystal consists of the heteropolyanion GaW12O 5−40 and H+ cations. The heteropolyanion GaW12O 5−40 is an independent unit and assumed to have the Keggin structure.

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References

  1. Zhang, X.M.; Shan, B.Z.; You, X.Z.; Fun, H.K.; Yip, B.C. Polyhedron 1997, 16(4), 713.

    Google Scholar 

  2. Kobayashi, A.; Sasaki, Y. Bull. Chem. Soc. Jap. 1975, 48(3), 885.

    Google Scholar 

  3. Niu, J.Y.; You, X.Z.; Duan, C.Y.; Fun, H.K.; Zhou, Z.Y. Inorg. Chem. 1996, 35(14), 4221.

    Google Scholar 

  4. Clark, C.J.; Hall, D. Acta Crystallogr. B 1976, 32, 1545.

    Google Scholar 

  5. Attanasio, D.; Bonamico, M.; Fares, V.; Imperatori, P.; Suber, L. J. Chem. Soc. Dalton Trans. 1990, 3221.

  6. Spirlet, M.R.; Busing, W.R. Acta Crystallogr. B 1978, 34, 907.

    Google Scholar 

  7. Niu, J.Y.; Wang, J.P.; Song, L.H.; Zhou, Z.Y. J. Inorg. Chem. 1998, 14(3), 303.

    Google Scholar 

  8. Yu, L.; Wang, J.; Chen, H. J. Solid State Chem. 1992, 97, 239.

    Google Scholar 

  9. Wery, S.J.; Gutierrez-Zorrilla, J.M.; Luque, A.; et al. Polyhedron 1998, 8, 1247.

    Google Scholar 

  10. Zhang, X.M.; Shan, B.Z.; You, X.Z.; Fun, H.K.; Yip, B.C. Polyhedron 1996, 95.

  11. Fun, H.K.; Chinnakali, K.; Yip, B.C.; Niu, J.Y.; Wang, J.P. Acta Crystallogr. C 1998, 54, 327.

    Google Scholar 

  12. Neier, A.; Trojanowski, C.; Mattes, R. J. Chem. Soc. Dalton Trans. 1995, 2521.

  13. Williamson, M.M.; Bouchard, D.A.; Hill, C.L. Inorg. Chem. 1987, 26, 1436.

    Google Scholar 

  14. Niu, J.Y.; Wang J.P.; Bo, Y. J. Chem. Crystallogr. 2000, 30(1), 43.

    Google Scholar 

  15. Strandberg, R. Acta Crystallogr. B 1977, 33, 3090.

    Google Scholar 

  16. Strandberg, R.; Hedman, B. Acta Crystallogr. B 1982, 38,773.

    Google Scholar 

  17. Liu, J.F.; Wang, J.P.; Qu, L.Y.; Chen, Y.G. J. Inorg. Chem. 1992, 8, 311.

    Google Scholar 

  18. Sheldrick, G.M. SHELXL-97 Program for Crystal Structure Refinement; University of Göttingen: Germany, 1997.

    Google Scholar 

  19. Keggin, J.F. Nature 1933, 131, 908.

    Google Scholar 

  20. Pope, M.T. Heteropoly and Isopoly Oxometalates; Springer-Verlag: Berlin, 1983.

    Google Scholar 

  21. Brown, D.; Altermatt, D. Acta Crystallogr B 1985, 41, 244.

    Google Scholar 

Download references

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475001, People's Republic of China

    Jing-Yang Niu, Ming-Xue Li, Jing-Ping Wang & Yan Bo

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  1. Jing-Yang Niu
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  2. Ming-Xue Li
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  3. Jing-Ping Wang
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  4. Yan Bo
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Correspondence to Jing-Yang Niu.

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Niu, JY., Li, MX., Wang, JP. et al. Preparation and crystal structure of tungstogallate acid H5GaW12O40 . Journal of Chemical Crystallography 33, 799–803 (2003). https://doi.org/10.1023/A:1026115609282

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