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Electric Double Layer at the Membrane/Solution Interface in a Three-Layered Membrane System

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Abstract

Transport of ions through a three-layered membrane system at overlimiting currents is simulated mathematically. To allow for the space charge, the Poisson equation is used in both the first diffusion layer and the membrane. Two modes are shown to exist at overlimiting currents: a quasi-equilibrium state of the interface and a Schottky mode.

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Authors and Affiliations

  1. Kuban State University, ul. Stavropol'skaya 149, Krasnodar, 340040, Russia

    V. I. Zabolotskii & E. G. Lovtsov

Authors
  1. V. I. Zabolotskii
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  2. K. A. Lebedev
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  3. E. G. Lovtsov
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Zabolotskii, V.I., Lebedev, K.A. & Lovtsov, E.G. Electric Double Layer at the Membrane/Solution Interface in a Three-Layered Membrane System. Russian Journal of Electrochemistry 39, 1065–1072 (2003). https://doi.org/10.1023/A:1026115202386

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  • DOI: https://doi.org/10.1023/A:1026115202386

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