Skip to main content
SpringerLink
Log in

X-ray structure of dodecasodium tricopper(II)bis[nonatungstabismuthate(III) hydrate, a polyoxometalate salt containing α-B-BiW9O33 units

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The reaction of [Bi2W22O74(OH)2]12− with Cu2+ in hot aqueous solution in the presence of Na+ affords the polyoxometalate salt Na12[Cu3Bi2W18O66]⋅32H2O. Single-crystal X-ray analysis [monoclinic, space-group C2/m, a = 33.082(6) Å, b = 19.615(5) Å, c = 14.885(2) Å, β = 90.632(12)°, Z = 4; R(F) = 0.065 for 6029 data with I>σ (I), wR(F 2) = 0.135 for all 8793 independent reflections] shows that the anion [{Cu(H2O)}3{BiW9O33}2]12−, on a crystal mirror-plane, has noncrystallographic symmetry close to D3h. Two B-α-[BiIIIW9O33]9− units are linked by an equatorial belt of three Cu(H2O)2+ units. Three Na(H2O)2 + units are also attached in the equatorial plane. The bond geometry is square-pyramidal about each Cu atom and trigonal–prismatic about each Na.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Rogers, A.; Smith, F.E. J. Am. Chem. Soc. 1904, 26, 1474.

    Google Scholar 

  2. Souchay, P.; Leray, M.; Hervé, G. Comptes Rendus Acad. Sci. Paris 1970, C271, 1337.

    Google Scholar 

  3. Rodewald, D.; Jeannin, Y. Comptes Rendus Acad. Sci. Paris sér. IIc, 1998, 1, 175.

    Google Scholar 

  4. Loose I.; Droste, E.; Bösing, M.; Pohlmann, H.; Dickman, M.H.; Rosu, C.; Pope, M.T.; Krebs, B. Inorg. Chem. 1999, 3, 2688.

    Google Scholar 

  5. Rosu C.R.; Weakley, T.J.R. Acta Crystallogr. Sect. C 1999, 55, IUC9900034.

    Google Scholar 

  6. Ozawa, Y.; Sasaki, Y. Chem. Lett. 1987, 923.

  7. Botar, B.; Yamase, T.; Ishikawa, E. Inorg. Chem. Commun. 2000, 3, 579.

    Google Scholar 

  8. Rusu, R.; Barra, A.-L.; David, L.; Rusu, M.; Rosu, C.; Cozar, O.; Marcu, G. Dalton Trans. 2001, 2879.

  9. Rosu, C.; Rusu, D.; Nicoara, C.; Weakley, T.J.R. 5th FGIPS Meeting in Inorganic Chemistry, Toulouse, France, 1999, Abstract PA88. Preliminary report.

    Google Scholar 

  10. Botar, B.; Yamase, T.; Ishikawa, E. Inorg. Chem. Commun. 2001, 4, 551.

    Google Scholar 

  11. Krebs, B.; Klein, R. In Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity; Pope, M.T.; Muller, A., Eds.; Kluwer: Dordrecht, The Netherlands, 1994,p. 41.

    Google Scholar 

  12. Altomare, A.; Cascarano, G.; Giacovazzo, C.; Guagliardi, A.; Burla, M.C.; Polidori, G.; Camalli, N. J. Appl. Crystallogr. 1994, 27, 435.

    Google Scholar 

  13. TeXsan Software for Single-Crystal Structure Analysis, version 1.8; Molecular Structures Corporation, 3200A Research Forest Drive, The Woodlands, TX. 1997.

  14. Tourné, G.F.; Tourné, C.M. 6th European Crystallography Meeting, Barcelona, Spain, 1980. Abstracts.

  15. Robert, F.; Leyrie, M.; Hervé, G. Acta Crystallogr. Sect. B 1982, 38, 358–362.

    Google Scholar 

  16. Ding, J.; Ku, Y.; Wu, G.; Wang, B. Acta Chim. Sinica 1989, 356.

  17. Bösing, M.; Nöh, A.; Loose, I.; Krebs, B. J. Am. Chem. Soc. 1998, 120, 7252.

    Google Scholar 

  18. Mialane, P.; Marrot, J.; Rivière, E.; Nebout, J.; Hervé, G. Inorg. Chem. 2001, 40, 44.

    PubMed  Google Scholar 

  19. Kortz, U.; Al-Kassem, N.K.; Savelieff, M.G.; Al Kadi, N.A.; Sadakane, M. Inorg. Chem. 2001, 40, 4742.

    PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic Chemistry, Babes-Bolyai University, RO-3400, Cluj-Napoca, Romania

    Cristina Rosu & Dan Rasu

  2. Department of Chemistry, University of Oregon, Eugene, Oregon, 97403

    Timothy J.R. Weakley

Authors
  1. Cristina Rosu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Dan Rasu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Timothy J.R. Weakley
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Timothy J.R. Weakley.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rosu, C., Rasu, D. & Weakley, T.J. X-ray structure of dodecasodium tricopper(II)bis[nonatungstabismuthate(III) hydrate, a polyoxometalate salt containing α-B-BiW9O33 units. Journal of Chemical Crystallography 33, 751–755 (2003). https://doi.org/10.1023/A:1026103306556

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1026103306556

Search

Navigation