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Oligomerization of Caprolactam by the Acidolysis Reaction. Process Kinetics

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Fibre Chemistry Aims and scope

Abstract

The major difference in the reaction rates of acidolysis of CL with phthalic and adipic acids on one hand, and azelaic, sebacic, and stearic acids on the other hand, is demonstrated. The opinion is advanced that the high efficiency of adipic acid in the reaction of addition of the first molecule of CL is due to its capacity for intramolecular autoprotonation and addition of the next molecules is due to the appearance of overall acid catalysis.

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REFERENCES

  1. A. S. Sphital'nyi, E. A. Meos, and E. A. Serkov, Zh. Obshch. Khim., 22, 1266 (1952).

    Google Scholar 

  2. A. S. Sphital'nyi, K. E. Perepelkin, and E. A. Meos, Zh. Obshch. Khim., 24, 447 (1954).

    Google Scholar 

  3. A. S. Sphital'nyi, M. A. Shpital'nyi, and Ya. A. Kharit, Khim. Volokna, No. 3, 13 (1960).

    Google Scholar 

  4. T. G. Majury, J. Polym. Sci., 31, 383 (1958).

    Google Scholar 

  5. Bi Syan'-tun and Van Bao-zhen, Gazofen'tsza Tusyun', 6, No. 3, 171 (1964); cited in: RZhkhim, No. 15, 149 (1966).

    Google Scholar 

  6. G. M. Barnett, A. J. MacArthur, and J. N. Hay, Eur. Polym. J., 3, No. 3, 321 (1967).

    Google Scholar 

  7. B. Lanska and J. Sebenda, Eur. Polym. J., 10, No. 2, 841 (1974).

    Google Scholar 

  8. B. Lanska and J. Sebenda, Collect. Czech. Chem. Communs., 40, No. 5, 1524 (1975).

    Google Scholar 

  9. L. N. Mizerovskii and Yu. M. Bazarov, Vysokomolek. Soedin., 17B, No. 3, 178 (1975).

    Google Scholar 

  10. L. N. Mizerovskii, S. N. Karaseva, et al., Khim. Volokna, No. 2, 12–16 (2003).

    Google Scholar 

  11. L. N. Mizerovskii, S. N. Karaseva, and V. G. Silant'eva, in: Proceedings of the 7th International Conference “Oligomers-200” [in Russian], Perm' (2000), p. 78.

  12. L. N. Mizerovskii, D. L. Siganov, et al., Vysokomolek. Soedin., 33A, No. 5, 967 (1991).

    Google Scholar 

  13. L. N. Mizerovskii, Yu. S. Paikachev, et al., Vysokomolek. Soedin., 13A, No. 5, 1109 (1971).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry of Solutions, Russian Academy of Sciences, Ivanovo

    L. N. Mizerovskii & S. N. Karaseva

  2. Ivanovo State Chemical Engineering University, Russia

    V. G. Silant'eva

Authors
  1. L. N. Mizerovskii
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  2. S. N. Karaseva
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  3. V. G. Silant'eva
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Mizerovskii, L.N., Karaseva, S.N. & Silant'eva, V.G. Oligomerization of Caprolactam by the Acidolysis Reaction. Process Kinetics. Fibre Chemistry 35, 183–188 (2003). https://doi.org/10.1023/A:1026101721466

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  • DOI: https://doi.org/10.1023/A:1026101721466

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