Abstract
Mechanism of electrochemical oxidative polymerization and formation of polymers based on the transition metal complexes are considered. The complexes under study are assumed to have the resonance structures and a highly reactive imino group (–N=CH–) in the macrocyclic ring. IR spectra of the bis(salicylidene)ethylenediamine ligand (H2Salen), [NiSalen] and [PdSalen] monomers, and the respective polymers are examined and used for the experimental substantiation of the proposed mechanism underlying the formation of conducting polymers.
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Shagisultanova, G.A., Kuznetsova, N.N. Conducting and Photoactive Polymers on the Basis of Transition Metal Complexes: Electrochemical Synthesis. Russian Journal of Coordination Chemistry 29, 703–709 (2003). https://doi.org/10.1023/A:1026072016285
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DOI: https://doi.org/10.1023/A:1026072016285