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Polymerization of ethylene catalyzed by titanocene(iii) -b-diketonate complex and MMAO

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Abstract

Ethylene polymerizations were performed with a catalytic system composed of titanocene(III)-β-diketonate complex such as [Cp2Ti(III)(1-benzoylacetonato)] or [Cp2Ti(III)(dibenzoylmethanato)] and MMAO. These catalysts are active for the polymerization of ethylene to give high-density polyethylene with high molecular weight.

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REFERENCES

  1. M. Bochman: J. Chem. Soc., Dalton Trans., 255 (1996).

  2. S.D. Ittel, L.K. Johnson, M. Brookhart: Chem. Rev., 100, 1169 (2000).

    Article  CAS  Google Scholar 

  3. H.G. Alt, A. Koppl: Chem. Rev., 100, 1205 (2000).

    Article  CAS  Google Scholar 

  4. G.W. Coates: Chem. Rev., 100, 1223 (2000).

    Article  CAS  Google Scholar 

  5. E.Y.-X. Chen, T.J. Marks: Chem. Rev., 100, 1391 (2000).

    Article  CAS  Google Scholar 

  6. L.S. Boffa, B.M. Novak: Chem. Rev., 100, 1479 (2000).

    Article  CAS  Google Scholar 

  7. W. Kaminsky, A. Laban: Applied Catalyst A General, 222, 47 (2001).

    Article  CAS  Google Scholar 

  8. B. Ray, T.G. Neyroud, M. Kapon, Y. Eichen, M.S. Eisen: Organometallics, 20, 3044 (2001).

    Article  CAS  Google Scholar 

  9. A. Zambelli, M. Caprio, A. Grassi, D.E. Bowen: Macromol. Chem. Phys., 201, 393 (2000).

    Article  CAS  Google Scholar 

  10. K. Hiraki, T. Inoue, H. Hirai: J. Polym. Sci., Part A-1, 8, 2543 (1970).

    Article  CAS  Google Scholar 

  11. T.H. Newman, M.T. Malanga: The Division program for the Orlando Meeting, Orlando, USA, Aug 25-29, 534 (1996).

  12. U.S. Pat. 5756610, Industrial Technology Research Institute, Hsinchu, invs.: Tasi J-C, Liu KK, Peng S-L, Wang S-J (1998).

  13. WO 96/13529, DSM NV, invs.: van Beek JAM, van Doremaele GHJ, Gruter GJM, Eggels GHME (1996).

  14. S.S. Yun, I.-H. Suh, E.H. Kim, S. Lee: J. Coord. Chem., 51, 219 (2000).

    CAS  Google Scholar 

  15. A.M. Bond, R. Colton, U. Englert, H. Hugel, F. Marken: Inorg. Chim. Acta., 235, 117 (1995).

    Article  CAS  Google Scholar 

  16. B. Rieger, X. Mu, D.T. Mallin, M.D. Rausch, J.C.W. Chien: Macromolecules, 23, 3559 (1990).

    Article  CAS  Google Scholar 

  17. J.C.W. Chien, R. Sugimoto: J. Polym. Sci., Part A, 29, 459 (1991).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Daejeon University, Daejeon, 300-716, Korea

    Samkeun Lee & Kyoung-Chae Seo

  2. Korea Research Institute of Chemical Technology, Daejeon, 305-600, Korea

    Dong-Koo Lee

  3. Department of Chemistry, Chungnam National University, Daejeon, 305-764, Korea

    Sock Sung Yun

Authors
  1. Samkeun Lee
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  2. Kyoung-Chae Seo
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  3. Dong-Koo Lee
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  4. Sock Sung Yun
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Lee, S., Seo, KC., Lee, DK. et al. Polymerization of ethylene catalyzed by titanocene(iii) -b-diketonate complex and MMAO. Reaction Kinetics and Catalysis Letters 80, 53–57 (2003). https://doi.org/10.1023/A:1026071923366

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