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Micellar and salt effects upon the oxidation of N,N-dimethylaniline by hexacyanoferrate(III)

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Abstract

The oxidation of N,N-dimethylaniline (DMA) by hexacyanoferrate (III) (Fe (CN)6 3-) has been studied in aqueous and micellar solutions of N,N-dimethyl- dodecylamine N-oxide (DDAO). The rate enhancement of the reaction in the presence of micelles has been explained with the pseudo- phase model of the kinetics.The dependence of the reaction rate on the nature of the salt cation has also been discussed.

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REFERENCES

  1. E.H. Cordes: Reaction Kinetics in Micelles.Plenum, New York 1973.

    Google Scholar 

  2. J.H. Fendler, E.J. Fendler: Catalysis in Micellar and Micromolecula System. Academic Press, New York 1975.

    Google Scholar 

  3. M. Gratzel: In Micellization, Solubilization and Microemulsion, Vol. 2, Ed. K.L. Mittal, p. 531. Plenum Press 1977.

  4. E.H. Gordes, C. Gitter: Prog. Bioorg. Chem., 2, 1 (1973).

    Google Scholar 

  5. R.M. Baraka, T.M. Haboush, A.A. El Khaldy, J.K.J. Salem: Colloid Surf., 202, 181 (2002)

    Google Scholar 

  6. J.K.J. Salem, R.M. Baraka, T.M. Haboush, A.A. El Khaldy: Tenside Surf. Det., 2, 23 (2002).

    Google Scholar 

  7. Sh.M. Zourab, E.M. Ezzo, H.J. Aila, J.K.J. Salem: Dispersion Sci. Technol., 24, 132 (2002).

    Google Scholar 

  8. R. Stewart: Oxidation Mechanism. W.A. Benjamin, Inc., New York 1964.

    Google Scholar 

  9. C. Hlrose, L, Sepulveda: J. Phys. Chem., 85, 3689 (1981).

    Article  Google Scholar 

  10. A. Rodrigues, M.M. Graciani, M.L. Moya: Langmuir, 12, 4094 (1986).

    Google Scholar 

  11. A. Rodrigues, M.M. Graciani, R. Balahura, M. Moya: J. Phys. Chem., 100, 16978 (1996).

    Article  Google Scholar 

  12. R. Prado-Gotor, R. Jimenez, P. Lopez, P. Perez, C. Gomez-Herrera, F. Sanchez: Langmuir, 14, 1539 (1998).

    Article  CAS  Google Scholar 

  13. E. Pramauro, E. Pelizzetti, S. Diekmann, J. Frahm: J. Inorg. Chem., 21, 2432 (1982).

    Article  CAS  Google Scholar 

  14. C.A. Bunton, A.A. Kamego, M.J. Minch, J.L. Klright: J. Org. Chem., 40, 1321 (1975)

    Article  CAS  Google Scholar 

  15. F. Del Rosso, A. Bartoletti, P. Di Profio, F. Germani, G. Savelli, A. Blasko, C.A. Bunton: J. Chem. Soc., Perkin Trans., 2,673 (1995).

    Google Scholar 

  16. J.F. Rathman, S.D. Christian: Langmuir, 6, 391 (1990).

    Article  CAS  Google Scholar 

  17. A. Fernandez, E. Iglesias, G.R. Luis, J.R. Leis: Langmuir, 11, 1917 (1995).

    Article  CAS  Google Scholar 

  18. C.A. Audeh, J.R. Lindsay Smith: J. Chem. Soc. B, 1280 (1970).

  19. R.K. Paul, F.R. James: Langmuir, 11, 3007 (1995).

    Article  Google Scholar 

  20. C.A. Bunton, F. Rivera, L. Sepulveda: J. Org. Chem., 43, 1166 (1978).

    Article  CAS  Google Scholar 

  21. C.A. Bunton: J. Mol. Liquids, 72, 231 (1997).

    Article  CAS  Google Scholar 

  22. L.S. Romsted: Micellization, Solubilization and Microemulsions,Vol. 1, Ed. K.L. Mittal, p. 509. Plenum Press 1977.

  23. M. Hiroshi, M. Shuichi, K. Rie: J. Phys. Chem. B., 101, 7378 (1977).

    Google Scholar 

  24. M.H. Abraham, H.S. Chadha, J.P. Dixon, C. Rafols, C. Treiner: J. Chem. Soc. Perkin Trans., 2, 887(1995).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Al- Azhar University, Gaza, P.O. Box 1277, PNA

    J. K. J. Salem

  2. Department of Chemistry, Al - Aqsa University, Gaza - PNA, Via Israel

    H. J. Y El- Aila

Authors
  1. J. K. J. Salem
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  2. H. J. Y El- Aila
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Salem, J.K.J., El- Aila, H.J.Y. Micellar and salt effects upon the oxidation of N,N-dimethylaniline by hexacyanoferrate(III). Reaction Kinetics and Catalysis Letters 80, 105–112 (2003). https://doi.org/10.1023/A:1026036310162

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