Skip to main content
Log in

Comparison of the Oxidation Rates of Some New Copper Alloys

  • Published:
Oxidation of Metals Aims and scope Submit manuscript

Abstract

Copper alloys were studied for oxidation resistance and mechanisms between 550 and 700°C, in reduced-oxygen environments expected in rocket engines, and their oxidation behaviors compared to that of pure copper. They included two dispersion-strengthened alloys (precipitation-strengthened and oxide-dispersion strengthened, respectively) and one solution-strengthened alloy. In all cases the main reaction was oxidation of Cu into Cu2O and CuO. The dispersion-strengthened alloys were superior to both Cu and the solution-strengthened alloy in oxidation resistance. However, factors retarding oxidation rates seemed to be different for the two dispersion-strengthened alloys.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. B. Morgan et al., Advanced Earth-to-Orbit Propulsion Technology 1988, Vol. II, J. Richmond and S. Wu, eds., NASA Conf. Publication 3012(1988).

  2. M. Murphy, et al., Advanced Earth-to-Orbit Propulsion Technology 1986, Vol. II, R. J. Richmond and S. Wu, eds., NASA Conf. Publication 2437 (1986) p. 580.

  3. D. L. Ellis and D. J. Keller, NASA Contract Report CR 2000–210055, NASA GRC, Cleveland, OH, June 2000.

  4. L. U. J. T. Ogbuji, to appear in Materials at High Temperatures.

  5. D. E. Davies and U. R. Evans, “The Oxidation of Iron at 175 to 3508C”, Proc. Roy. Soc. Lond. 225A, 443(1954).

    Google Scholar 

  6. L. U. J. T. Ogbuji, J. Electrochem. Soc. 145(8), 2876(1998).

    Google Scholar 

  7. L. U. J. T. Ogbuji, J. Electrochem. Soc. 145(8), 2876(1998).

    Google Scholar 

  8. K. G. Nickel, Corrosion of Advanced Ceramics: Measurement and Modeling, K. G. Nickel, ed. (Kluwer Publishers, Boston, USA, 1994) p. 59.

    Google Scholar 

  9. A. Ronnquist and H. Fischmeister, J. Inst. of Metals, 89, 65(1960–61).

    Google Scholar 

  10. S. Mrowec and A. Stoklosa, Oxid. Met. 3(3), 290(1971).

    Google Scholar 

  11. J.-H. Park and K. Natesan, Oxid Met. 39(5/6), 411(1993).

    Google Scholar 

  12. M. P. Brady, P. F. Tortorelli, and L. R. Walker, Mat. High Temp. 17(2), 235(2000).

    Google Scholar 

  13. I. G. Wright, V. Nagarajan, and J. Stringer, Corrosion Sci. 35(5–8) 841(1993).

    Google Scholar 

  14. J. R. Groza, Mat. Charac. 31, 133(1993).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ogbuji, L., Humphrey, D. Comparison of the Oxidation Rates of Some New Copper Alloys. Oxidation of Metals 60, 271–291 (2003). https://doi.org/10.1023/A:1026019202691

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1026019202691

Navigation