Abstract
High-temperature x-ray diffraction is used to determine the lattice parameters of synthetic troilite (sealed-ampule method) and pyrrhotine prepared via thermal dissociation of natural pyrite. The results are presented in the form of best fit polynomials in temperature. The gaseous environment (helium or air) is found to have a significant effect on the temperature variation of the lattice parameters.
Similar content being viewed by others
REFERENCES
Vaughan, D., Sulfide Mineralogy: A Review with Special Reference to Phases of Interest in Hydrometallurgy, Proc. NATO Adv. Res. Inst., 1984, pp. 1–22.
Vaughan, D and Craig, J., Mineral Chemistry of Metal Sulfides, Cambridge: Cambridge Univ. Press, 1978. Translated under the title Khimiya sul'fidnykh mineralov, Moscow: Mir, 1981.
Novikov, G.V., Egorov, V.K., and Sokolov, Yu.A., Pirrotiny (Pyrrhotines), Moscow: Nauka, 1988.
Vanyukov, L.V., Isakova, R.A., and Bystrov, V.P., Termicheskaya dissotsiatsiya sul'fidov metallov (Thermal Dissociation of Metal Sulfides), Almaty: Nauka, 1978.
Putnis, A., Electron-Optical Observation on the ?-Transformation in Troilite, Science (Washington, D. C., 1883– 1974, vol. 186, pp. 439–440.
Koller-Besrest, F. and Collin, G., Structural Aspects of the ?-Transition in Stoichiometric FeS, J. Solid State Chem., 1990, vol. 84, no. 2, pp. 194–197.
Moldenhauer, W. and Briikner, W., Physical Properties of Nonstoichiometric Iron Sulfides Fe1 -x S near ?-Transition, Phys. Status Solidi A, 1976, vol. 34, pp. 565–571.
Bertant, E.F., Structure de FeS stoechiométrique, Bull. Soc. Fr. Mineral. Cristallogr., 1956, vol. 79, pp. 276–292.
Turkhan, Yu.E., Blankova, E.B., Kelarev, V.V., and Vakhmenin, A.P., Neutron and X-ray Diffraction Studies of Phase Transitions in Fe1.00S1 -x Sex Solid Solutions, Fizika metallov i ikh soedinenii (Physics of Metals and Their Compounds), Sverdlovsk: Ural. Gos. Univ., 1981, pp. 3–8.
Abishev, D.N. and Baltynova, N.Z., Termomagnitnoe obogashchenie piritsoderzhashchego syr'ya (Thermomagnetic Dressing of Pyrite-Containing Raw Materials), Almaty: Nauka, 1986.
Blankova, E.B., Skryabina, S.N., and Turkhan, Yu.E., Thermal Expansion of Iron Monosulfide, Fiz. Met. Ikh Soedin., 1976, no. 4, pp. 3–8.
-x S, Geokhimiya, 1982, no. 8, pp. 1189–1194.
Vershinin, A.D., Selivanov, E.N., and Danilushkin, A.L., Thermal Expansion and Decomposition of FeS2 -x and CuFeS2 -x , Neorg. Mater., 1998, vol. 34, no. 12, pp. 1423–1427 [Inorg. Mater. (Engl. Transl.), vol. 34, no. 12, pp. 1198–1202].
Vershinin, A.D. and Selivanov, E.N., Thermal Expansion of Arsenopyrite in Helium and Air, Neorg. Mater., 2000, vol. 36, no. 6, pp. 672–676 [Inorg. Mater. (Engl. Transl.), vol. 36, no. 6, pp. 551–555].
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Selivanov, E.N., Vershinin, A.D. & Gulyaeva, R.I. Thermal Expansion of Troilite and Pyrrhotine in Helium and Air. Inorganic Materials 39, 1097–1102 (2003). https://doi.org/10.1023/A:1026007729489
Issue Date:
DOI: https://doi.org/10.1023/A:1026007729489