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Kinetic method by using calorimetry to mechanism of epoxy-amine cure reaction

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Abstract

The results of using the calorimetric method to the mechanism of epoxy-amine cure reaction are presented. Under isothermal conditions, the cure kinetics was analysed by the Mangelsdorf approach. The kinetics of epoxy-amine cure reaction has clearly shown that interaction between epoxy and amine-groups follow the second-order rate law. This finding is important evidence in favour of conception of structured reactive medium during epoxy-amine cure reaction.

It is found that amine excess over epoxide reveals the clear catalytic action. Possible mechanism involving the complex formation between initial reagents is considered.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Kosygina str. 4, Moscow, 117334, Russia

    R. M. Vinnik

  2. Chemistry Department, Moscow State University, Moscow, 119899, GSP-3, Russia

    V. A. Roznyatovsky

Authors
  1. R. M. Vinnik
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  2. V. A. Roznyatovsky
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Vinnik, R.M., Roznyatovsky, V.A. Kinetic method by using calorimetry to mechanism of epoxy-amine cure reaction. Journal of Thermal Analysis and Calorimetry 73, 819–826 (2003). https://doi.org/10.1023/A:1025886615246

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  • DOI: https://doi.org/10.1023/A:1025886615246

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