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Thermochemistry of the complexes of some microelements and histidine

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Abstract

Solid complexes of M(His)2Cl2·nH2O (M=Mn, Co, Ni, Cu) of MnCl2·6H2O, CoCl2·6H2O, NiCl2·6H2O, CuCl2·2H2O and L-α-histidine (His) have been prepared in 95% ethanol solution and characterized by elemental analyses, chemical analyses, IR and TG-DTG. The constant-volume combustion energies of the complexes have been determined by a rotating-bomb calorimeter. And the standard enthalpies of formation of the complexes have been calculated as well.

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Authors and Affiliations

  1. Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi'an, 710069, P.R. China

    S. Chen, Sh Gao, X. Yang & R. Hu

  2. 330047 Nanchang Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University Institute of Modern Applied Chemistry, Xi'an, 710069, P.R. China

    Q. Shi

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  1. S. Chen
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  2. Sh Gao
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  3. X. Yang
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  4. R. Hu
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Chen, S., Gao, S., Yang, X. et al. Thermochemistry of the complexes of some microelements and histidine. Journal of Thermal Analysis and Calorimetry 73, 967–975 (2003). https://doi.org/10.1023/A:1025871606585

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