Abstract
The vapor-phase cyclohexane oxidative dehydrogenation has been investigated over several catalysts. A typical catalyst for total oxidation, as Mn2O3, materials applied in the field of oxide hydrogenation reactions, as silica-supported vanadia- and niobia-based catalysts, V-, Fe-, and Ce-phosphates used for partial oxidation reactions and ZSM5 zeolite, protonic and Co exchanged, have been tested. Over almost all the catalysts, benzene is the main product obtained, although cyclohexene is obtained with high selectivity at low conversion on phosphate catalysts.
Similar content being viewed by others
References
K. Weissermel and H.-J. Arpe, Industrial Organic Chemistry, 3rd ed. p. 240.
U. Schuchardt, D. Cardoso, R. Sercheli, R. Pereira, R. S. da Cruz, M. C. Guerreiro, D. Mandelli, E. V. Spinaci and E. L. Pires, Appl. Catal. A: Gen. 211 (2001) 1.
K. Weissermel and H.-J. Arpe, Industrial Organic Chemistry, 3rd ed. p. 345.
J. Blomberg, P. J. Schoenmakers and U. A. Th. Brinkman, J. Chromatogr. A, 972 (2002) 137–173.
K. Nishi, S. Komai, K. Inagaki, A. Satsuma and T. Hattori, Appl. Catal. A: Gen. 223 (2002) 187–193.
D. Sanfilippo, F. Buonomo, G. Fusco and I. Miracca, in Natural Gas Conversion V, P. A. Parmaliana, D. Sanfilippo, F. Frusteri, A. Vaccari and F. Arena (eds) (Elsevier, Amsterdam, 1998) pp. 919–924.
H. H. Kung, Advan. Catal. 40 (1994) 1.
C. Hettige, K. R. R. Mahanama and D. P. Dissanayake, Chemosphere 43 (2001) 1079.
M. Ai, Catal. Today 52 (1999) 65–69.
R. A. W. Johnstone, J. Liu and D. Whittaker, J. Mol. Catal. A: Chem. 174 (2001) 159–168.
E. L. Pires, M. Wallau and U. Schuchardt, J. Mol. Catal. A: Chem. 136 (1998) 69–74.
G. Busca and G. Centi, J. Am. Chem. Soc. 111(1) (1989).
J. M. Millet, D. Rouzies and J. C. Vedrine, Appl. Catal. A: Gen. 124 (1995) 205–219.
M. Baldi, V. Sanchez Escribano, J. M. Gallardo Amores, F. Milella and G. Busca, Appl. Catal. B: Environ. 17 (1998) L175–182.
J. G. Eon, R. Olie and J. C. Volta, J. Catal. 145 (1994) 318–326.
C. Resini, M. Panizza, F. Raccoli, M. Fadda, G. Busca, E. Fernandez López and V. Sanchez Escribano, Submitted paper.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Panizza, M., Resini, C., Busca, G. et al. A Study of the Oxidative Dehydrogenation of Cyclohexane Over Oxide Catalysts. Catalysis Letters 89, 199–205 (2003). https://doi.org/10.1023/A:1025863828152
Issue Date:
DOI: https://doi.org/10.1023/A:1025863828152