Skip to main content
SpringerLink
Log in

Comparison of 18O Isotopic Exchange After and During the Interaction of N2O, NO, and NO2 with Fe Ions in Ferrierites

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Nitrous oxide deposits its oxygens on Fe-ferrierites at 200–250 °C in contrast with nitric oxide and nitrogen dioxide. This oxygen is readily exchangeable for 18O2 at room temperature and the reaction proceeds via a single-step exchange mechanism. All three nitrogen oxides in a mixture with 18O labeled dioxygen undergo isotopic exchange (IE) at 200–250 °C, N2O via the same single-step mechanism, while NO and NO2 react via a multiple-step mechanism. Zeolitic oxygens participate in IE above 250 °C during temperature-programmed desorption of surface species formed in the reaction of nitrogen oxides with 18O2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. S. Ovanesyan, A. A. Steinman, V. I. Sobolev, K. A. Dubkov and G. I. Panov, Kinet. Katal. 39 (1998) 863.

    Google Scholar 

  2. G. I. Panov, A. K. Uriarte, M. A. Rodkin and V. I. Sobolev, Catal. Today 41 (1998) 365.

    Google Scholar 

  3. G. I. Panov, V. I. Sobolev and A. S. Kharitonov, J. Mol. Catal. 61 (1990) 85.

    Google Scholar 

  4. V. I. Sobolev, G. I. Panov, A. S. Kharitonov, V. N. Romannikov, A. M. Volodin and K. G. Ione, J. Catal. 139 (1993) 435.

    Google Scholar 

  5. G. I. Panov, A. S. Kharitonov and V. I. Sobolev, Appl. Catal. A: Gen. 98 (1993) 1.

    Google Scholar 

  6. G. I. Panov, V. I. Sobolev, K. A. Dubkov, V. N. Parmon, N. S. Ovanesyan, A. E. Shilov and A. A. Shteinman, React. Kinet. Catal. Lett. 61 (1997) 251.

    Google Scholar 

  7. J. Novakova, M. Lhotka, Z. Tvaruzkova and Z. Sobalík, Catal. Lett. 83 (2002) 215.

    Google Scholar 

  8. A. S. Kharitonov, G. A. Sheveleva, G. I. Panov, Ye. A. Paukshtis and V. N. Romannikov, Appl. Catal. A98 (1993) 33.

    Google Scholar 

  9. F. Heinrich, C. Schmidt, E. Loffler, M. Menzel and W. Grunert, J. Catal. 212 (2002) 157.

    Google Scholar 

  10. P. Kubanek, B. Wichterlova and Z. Sobalík, J. Catal. 211 (2002) 109.

    Google Scholar 

  11. S. Perathoner, F. Pino, G. Centi, G. Giordano, A. Katovic, J. B. Nagy, K. Lazar and P. Fejes, Stud. Surf. Sci. Catal. 142 (2002) 503.

    Google Scholar 

  12. Z. Sobalík, A. Vondrova, Z. Tvaruzkova, B. Wichterlova, Catal. Today 75 (2002) 347.

    Google Scholar 

  13. C. M. Fu, V. N. Korchak and W. K. Hall, J. Catal. 68 (1981) 166.

    Google Scholar 

  14. J. Leglise, J. O. Petunchi and W. K. Hall, J. Catal. 86 (1984) 392.

    Google Scholar 

  15. J. Valyon, W. S. Millman and W. K. Hall, Catal. Lett. 24 (1994) 215.

    Google Scholar 

  16. K. Klier, J. Novakova and P. Jíru, J. Catal. 2 (1963) 479.

    Google Scholar 

  17. J. Novakova, Catal. Rev. (1970) 93.

Download references

Author information

Authors and Affiliations

  1. Academy of Sciences of the Czech Republic, J. Heyrovský Institute of Physical Chemistry, Dolejškova 3, 182 23, Prague 8, Czech Republic

    J. Nováková & Z. Sobalik

Authors
  1. J. Nováková
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. Sobalik
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nováková, J., Sobalik, Z. Comparison of 18O Isotopic Exchange After and During the Interaction of N2O, NO, and NO2 with Fe Ions in Ferrierites. Catalysis Letters 89, 243–247 (2003). https://doi.org/10.1023/A:1025762714948

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1025762714948

Search

Navigation