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Alkylation of Isobutane with Butenes on Zirconium Sulfate Catalysts

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Abstract

Sulfated zirconia catalysts supported on silica gel and aluminum oxide were prepared by impregnation, and their structure and acid-base and catalytic properties were studied. The parameters of synthesis and characteristics of this catalyst, which ensure high activity and selectivity in liquid-phase alkylation of isobutane with butenes, were determined.

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References

  1. Gembicki, S., Proc. 12th Int. Congr. on Catalysts, Stud. Surf. Sci. Catal., 2000, vol. 130, pp. 147-155.

    Google Scholar 

  2. Yadav, G. and Nair, J., Microporous Mesoporous Mater., 1999, vol. 33, pp. 1-48.

    Google Scholar 

  3. Guo, C., Yao, S., Cao, J., and Qian, Z., Appl. Catal. A, 1994, vol. 107, no. 2, pp. 229-238.

    Google Scholar 

  4. Corma, A., Juan-Rajadell, M., Lopez-Nieto, J., et al., Appl. Catal. A, 1994, vol. 111, no. 1, pp. 175-189.

    Google Scholar 

  5. Corma, A., Martinez, A., and Martinez, C., J. Catal., 1994, vol. 149, no. 1, pp. 52-60.

    Google Scholar 

  6. Corma, A., Martinez, A., and Martinez, C., Appl. Catal. A, 1996, vol. 144, no. 1, pp. 249-268.

    Google Scholar 

  7. Hess, A. and Kemnitz, E., Appl. Catal. A, 1997, vol. 149, no. 2, pp. 373-389.

    Google Scholar 

  8. Das, D. and Chakrabarty, D., Energy Fuels, 1998, vol. 12, no. 1, pp. 109-114.

    Google Scholar 

  9. Gore, R.B. and Thomson, W.J., Appl. Catal. A, 1998, vol. 168, no. 1, pp. 23-32.

    Google Scholar 

  10. Zalewski, D., Alerasool, S., and Doolin, P., Catal. Today, 1999, vol. 53, no. 3, pp. 419-432.

    Google Scholar 

  11. Xiao, X., Tierney, J., and Wender, I., Appl. Catal. A, 1999, vol. 183, no. 1, pp. 209-219.

    Google Scholar 

  12. Song, X. and Sayari, A., Catal. Rev.-Sci. Eng., 1996, vol. 38, no. 3, pp. 329-412.

    Google Scholar 

  13. Ivanov, A.V. and Kustov, L.M., Ross. Khim. Zh., 2000, no. 2, pp. 21-52.

    Google Scholar 

  14. Luy, L., Yori, J., Castro, A., and Parera, J., React. Kinet. Catal. Lett., 1988, vol. 36, no. 2, pp. 275-283.

    Google Scholar 

  15. Grau, J., Vera, C., and Parera, J., Appl. Catal. A, 1998, vol. 172, no. 2, pp. 311-326.

    Google Scholar 

  16. Vera, C., Pieck, C., Shimizu, K., and Parera, J., Proc. 7th Int. Symp. on Scientific Bases for the Preparation of Heterogeneous Catalysts, Stud. Surf. Sci. Catal., 1998, vol. 118, pp. 369-376.

    Google Scholar 

  17. Lei, T., Xu, J., Tang, Y., et al., Appl. Catal. A, 2000, vol. 192, no. 1, pp. 181-188.

    Google Scholar 

  18. Guo, C. and Yu, Z., Proc. Int. Symp. on Acid-Base Catalysis II, Stud. Surf. Sci. Catal., 1993, vol. 90, pp. 543-548.

    Google Scholar 

  19. Dzis'ko, V.A., Osnovy metodov prigotovleniya katalizatorov (Foundations of Methods for Catalyst Preparation), Novosibirsk: Nauka, 1983.

    Google Scholar 

  20. Physical and Chemical Aspects of Adsorbents and Catalysts, Linsen, B.G., Ed., London: Academic, 1970.

    Google Scholar 

  21. Laizet, J., Soiland, A., Leglise, J., and Duchet, J., Top. Catal., 2000, vol. 10, no. 1, pp. 89-97.

    Google Scholar 

  22. Paukshtis, E.A., Infrakrasnaya spektroskopiya v geterogennom kislotno-osnovnom katalize (Infrared Spectroscopy in Heterogeneous Acid_Base Catalysis), Novosibirsk: Nauka, 1992.

    Google Scholar 

  23. Spielbauer, D., Mekhemer, G., Zaki, M., and Knozinger, H., Catal. Lett., 1996, vol. 41, no. 1, pp. 101-109.

    Google Scholar 

  24. Morterra, C., Cerrato, G., and Pinna, F., Spectrochim. Acta, A, 1999, vol. 55, no. 1, pp. 95-103.

    Google Scholar 

  25. Morterra, C., Cerrato, G., and Bolis, E.A., J. Chem. Soc., Faraday Trans., 1997, vol. 93, pp. 1179-1185.

    Google Scholar 

  26. Paukshtis, E.A., Duplyakin, V.K., Finevich, V.P., et al., Proc. 12th Int. Congr. on Catalysis, Stud. Surf. Sci. Catal., 2000, vol. 130, pp. 2543-2548.

    Google Scholar 

  27. Dorogochinskii, A.Z., Lyuter, A.V., and Vol'pova, E.G., Sernokislotnoe alkilirovanie izoparafinov olefinami (Sulfuric Acid Alkylation of Isoparaffins with Olefins), Moscow: Nauka, 1970.

    Google Scholar 

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Lavrenov, A.V., Perelevskii, E.V., Finevich, V.P. et al. Alkylation of Isobutane with Butenes on Zirconium Sulfate Catalysts. Russian Journal of Applied Chemistry 76, 550–557 (2003). https://doi.org/10.1023/A:1025718732600

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