Abstract
The equilibrium between a copper-nickel alloy and an oxide melt in the Cu2O-NiO-SiO2 system was studied experimentally. The distribution coefficients of nickel were determined as a function of the content of silicon dioxide, and the ratio of activity coefficients of nickel and copper oxides at 1300°C was found.
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Onishchin, B.P., Khe Khuankhua, Tsemekhman, L.Sh., et al., Tsvetn. Met., 1998, no. 1, pp. 26-29.
Miroevskii, G.P., Golov, A.N., and Koklyanov, E.B., Tsvetn. Met., 2001, no. 2, pp. 41-47.
Golov, A.N., A Study and Development of Ecologically Pure Autogenous Technology for Processing of Low-Iron Copper-Rich Concentrates To Obtain Copper with Prescribed Composition, Cand. Sci. (Chem.) Dissertation, Moscow, 2001.
RF Patent 2 169 202.
Landolt, C., Dutton, A., Fritz, A., and Segsworth, S., Proc. Paul E. Queneau Int. Symp. Extractive Metallurgy of Copper, Nickel and Cobalt, 1993, vol. 2, pp. 1497-1527.
Fedorova, N.A., Tsymbulov, L.B., and Tsemekhman, L.Sh., Zh. Prikl. Khim., 2002, vol. 75, no. 4, pp. 535-539.
Kulkarni, A.D. and Johnson, R.E., Met. Trans., 1973, vol. 4, pp. 1723-1727.
Kubaschevski, O. and Alcock, C.B., Metallurgical Thermochemistry, Oxford: Pergamon, 1979.
Berezhnoi, A.S., Karyakin, L.I., and Dudavskii, Dokl. Akad. Nauk SSSR, 1952, no. 83, pp. 399-401.
Berezhnoi, A.S. and Karyakin, L.I., Tsvetn. Met., 1955, no. 2, pp. 26-33.
Gadalla, A.M., Ford, W.F., and White, I., Trans. Brit. Ceram. Soc., 1963, vol. 62, no. 1, pp. 45.
Ust'yantsev, V.M., Sudakova, L.P., and Bessonov, A.F., Zh. Neorg. Khim., 1966, vol. 11, no. 5, pp. 1177-1182.
Toropov, N.A., Barzakovskii, V.P., Lapin, V.V., et al., Diagrammy sostoyaniya silikatnykh sistem: Spravochnik (Phase Diagrams of Silicate Systems: Reference Book), Moscow, 1970, issue 2.
Phillips, B., Hutta, J.J., and Warshaw, I., J. Am. Ceram. Soc., 1963, vol. 46, no. 12, pp. 579-583.
Rog, G. and Borchardt, G., J. Chem. Thermodyn., 1984, vol. 16, pp. 1103-1105.
Taylor, R.W. and Schmalzried, H.J., J. Phys. Chem., 1964, vol. 68, pp. 2444-2449.
O'Neill, H.St.C., Am. Mineralogist., 1987, vol. 72, pp. 280-291.
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Fedorova, N.A., Tsymbulov, L.B. & Tsemekhman, L.S. Influence of SiO2 on the Equilibrium in the Cu-Ni-Cu2O-NiO System. Russian Journal of Applied Chemistry 76, 526–530 (2003). https://doi.org/10.1023/A:1025706329874
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DOI: https://doi.org/10.1023/A:1025706329874