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1,3-Alternate and C-1,2-Alternate Tetrahomodioxacalix[4]crowns. Crystal Structures and Metal Ion Complexation

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Abstract

Two novel tetrahomodioxacalix[4]crowns with crown-5 and crown-6 rings weresynthesized. From X-ray crystal structures, homooxacalix[4]crown-5 (3) andhomooxacalix[4]crown-6 (2) were found to be in the 1,3-alternate and theC-1,2-alternate conformations, respectively. Homooxacalix[4]crown-5 (1)shows a marked selectivity for cesium ion over other metal ions tested.

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Authors and Affiliations

  1. Department of Chemistry, Sookmyung Women's University, Seoul, 140-742, Korea

    K. No, Hye J. Chung & Hyun J. Yu

  2. Department of Chemistry, Konyang University, Nonsan, 320-711, Korea

    Seung H. Yang & Kwan H. Noh

  3. CEA/Saclay, DSM/DRECAM/SCM (CNRS URA 331), B{a}t. 125, 91191, Gif-sur-Yvette, France

    P. Thuéry

  4. ECPM (CNRS UMR 7512), 25, rue Becquerel, Strasbourg, F-67087 Cedex, France

    J. Vicens

  5. Department of Chemistry, Dankook University, Seoul, 140-714, Korea

    Jong S. Kim

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  1. K. No
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Correspondence to Jong S. Kim.

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No, K., Chung, H.J., Yu, H.J. et al. 1,3-Alternate and C-1,2-Alternate Tetrahomodioxacalix[4]crowns. Crystal Structures and Metal Ion Complexation. Journal of Inclusion Phenomena 46, 97–103 (2003). https://doi.org/10.1023/A:1025672102973

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