Abstract
The dependence of the NMR chemical shift in the system containing complexes of a paramagnetic cation PL and PL2 on the concentration of a diamagnetic salt was simulated. The complexation in the system paramagnetic ion (Tm3 +)-diamagnetic ion (Mg2 +)-carboxylic acid (acetic, propionic, n-butyric) was studied experimentally. The effect of the second cation on the calculated complexation constants was detected.
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Panyushkin, V.T., Sukhno, I.V. & Vodopetova, N.L. Complexation in the System Paramagnetic Ion (Tm3 +)-Diamagnetic Ion (Mg2 +)-Carboxylic Acid. Russian Journal of General Chemistry 73, 507–510 (2003). https://doi.org/10.1023/A:1025663730550
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DOI: https://doi.org/10.1023/A:1025663730550