Abstract
Two benzo-18-crown-6 (B18-C-6) complexes: [Na(B18-C-6)]2[Pd(SCN)4](H2O)({bf 1}) and [Na(B18-C-6)]2[Pt(SCN)4]...0.5C2H4C12 (2)have been synthesized and characterized by elemental analysis, IR spectrum and X-raydiffraction analysis. The crystal of complex 1 belongs to monoclinic, space group P21/n with cell dimensions, a = 1.0481(3), b = 1.2864 (3), c = 1.7003 (4) nm, β = 93.626(4)°, V = 2.2879 (9) nm3, Z = 2, Dcalcd = 1.491 g/cm3, F(000) = 1060, R1 = 0.0562, wR2 = 0.1412 and 2 is triclinic, spacegroup P1 with cell dimensions, a = 0.9581(3), b = 1.2173 (3), = 2.1198 (6) nm, α = 79.522(4), β = 77.911(4), γ = 78.617(4)°, V = 2.3442(11) nm3 Z = 2, Dcalcd = 1.626 g/cm3, F(000) = 1154, R1 = 0.0515, wR2 = 0.0612.Two complexes show one-dimensional chain of [Na(B18-C-6)]+ complex cations and [M(SCN)4]2- (M = Pd, Pt) complex anion bridged by Na–O–Na interactions of H2O molecule or Na-O bond of B18-C-6 between adjacent [Na(B18-C-6)]+ units respectively.
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References
C.J. Pedersen: J. Am. Chem. Soc. 89, 7019 (1967).
S.R. Cooper: Crown Ether Compounds: Toward Future Applications, VCH, New York (1992).
N. Komia, T. Naota, and S.-I. Murahashi: Tetrahedron Lett. 37, 1633 (1996).
D.L. Clark, D.W. Keogh, and C.L. Palmer: Angew. Chem. Int. Ed. 37, 164 (1998).
T. Nakamura, T. Akutagawa, K. Honda, A.E. Underhill, A.T. Coomber, and R.H. Friend: Nature 394, 159 (1998).
R.M. Izatt, K. Pawlak, and J.S. Bradshaw: Chem. Rev. 91, 1721 (1991).
J.W. Steed: Coord. Chem. Rev. 215, 171 (2001).
D.L. Hughes, C.L. Mortimer, and M.R. Truter: Inorg. Chim. Acta 29, 43 (1978).
D.S. Shephard, B.F.G. Johnson, J. Matters, and S. Parsons: J. Chem. Soc. Dalton Trans. 2289 (1998).
J. Lipkowski, M.S. Fonari, V.C. Kravtsov, Y.A. Simonov, E.V. Ganin, and V.O. Gelmboldt: J. Chem. Crystallogr. 26, 823 (1996).
K.-F. Tebbe and I.Z. Dombrowski: Anorg. Allg. Chem. 625, 167 (1999).
J. Pickardt and D. Dechert: Anorg. Allg. Chem. 625, 153 (1999).
H. Haser and K. Huml: Acta Cryst. B34, 1812 (1978).
J. Pickardt and P. Wischlinski: Anorg. Allg. Chem. 625, 1527 (1999).
J. Pickardt and P.Z. Wischlinski: Naturforsch. 54B, 747 (1999).
A.B. Charette, J.-F. Marcoux, and B.-J. Francine: J. Am. Chem. Soc. 118, 6793 (1996).
Y. Liu, J.M. Dou, L.Y. Zhu, D.Z. Sun, and P.J. Zheng: Indian J. Chem. 39A, 983 (2000).
J.M. Dou, X.M. Song, Y. Liu, X. Li, P.J. Zheng, C.X. Du, and Y. Zhu: Acta Chim. Sinica 59, 729 (2001) (in Chinese).
Z.X. Li, Z.H. Zhong, T. Wang, D.C. Li, D.Q. Wang, J.M. Dou, and P.J. Zheng: Acta Chim. Sinica 60, 1465 (2002) (in Chinese).
J.M. Dou, Y. Liu, D.Z. Sun, X. Li, P.J. Zheng, C.X. Du, and Y. Zhu: Acta Chim. Sinica 59, 918 (2001) (in Chinese).
J.M. Dou, D.C. Li, Q.J. Yu, Y. Liu, L.Q. Xu, W.H. Bi, W. Yong, and P.J. Zheng: Acta Chim. Sinica 59, 2162 (2001) (in Chinese).
D.Q. Wang, Q.J. Yu, and J.M. Dou: Chin. J. Chem. 20, 189 (2002).
D.Z. Zhu, X.M. Song, J.M. Dou, Y. Liu, and D.Q. Wang: Chin. J. Chem. 20, 424 (2002).
D.Z. Zhu, T.Wang, X.M. Song, J.M. Dou, D.C. Li, D.Q.Wang, M.M. Wu, and Y.Q. Gao: Acta Chim. Sinica 60, 910 (2002) (in Chinese).
D.Z. Zhu, X.M. Song, J.M. Dou, Y. Liu, D.Q. Wang, W. Yong, and P.J. Zheng: J. Chin. Inorg. Chem. 18, 697 (2002) (in Chinese).
Z.H. Zhang, J.M. Dou, Y. Liu, D.Q. Wang, W. Yong, and P.J. Zheng, C.X. Du, and Y. Zhu: Acta Chim. Sinica 60, 1645 (2002) (in Chinese).
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Li, DC., Li, ZX., Dou, JM. et al. One-dimensional Chain Crown Ether Complexes. Synthesis and Crystal Structure of Benzo-18-Crown 6 Complexes with Na 2 [M(SCN) 4 ] (M = Pd, Pt). Journal of Inclusion Phenomena 46, 83–88 (2003). https://doi.org/10.1023/A:1025658324777
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DOI: https://doi.org/10.1023/A:1025658324777