Abstract
The kinetics of heterolysis of 1-methyl-1-chlorocyclohexane in six protic and eight aprotic solvents at 25-50°C was studied by the verdazyl method; v = k[RCl], E1 mechanism. The correlation analysis of the solvent effects on the activation free energy ΔG ≠, enthalpy ΔH ≠, and entropy ΔS ≠ of heterolysis of 1-methyl-1-chlorocyclohexane and 1-methyl-1-chlorocyclopentane was performed for the same sets of solvents.
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Dvorko, G.F., Koshchii, I.V. & Ponomareva, E.A. Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXVI.1 Solvent Effect on the Activation Parameters of Heterolysis of 1-Methyl-1-chlorocyclohexane. Correlation Analysis of Solvation Effects in Heterolysis of 1-Methyl-1-chlorocyclohexane and 1-Methyl-1-chlorocyclopentane. Russian Journal of General Chemistry 73, 569–574 (2003). https://doi.org/10.1023/A:1025640520072
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DOI: https://doi.org/10.1023/A:1025640520072