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Modeling of Eu3+ Energy Levels in Complexes with 1,10-Phenanthroline Derivatives

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Abstract

The experimental electronic spectra of the Eu3+ ion in three groups of the Eu complexes (β-diketonates, acetates, and nitrates) with the 1,10-phenanthroline derivatives were used to calculate the crystal field parameters for the model of the nearest environment of this ion with the C 2ν point group symmetry. It was shown that these parameters can be used for estimating the coordination number of the metal cation and establishing the structural peculiarities.

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Authors and Affiliations

  1. Institute of Radio Engineering and Electronics, Russian Academy of Sciences, Moscow, Russia

    L. N. Puntus & V. F. Zolin

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  1. L. N. Puntus
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  2. V. F. Zolin
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Puntus, L.N., Zolin, V.F. Modeling of Eu3+ Energy Levels in Complexes with 1,10-Phenanthroline Derivatives. Russian Journal of Coordination Chemistry 29, 574–581 (2003). https://doi.org/10.1023/A:1025166522469

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