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Impedance of Indium(III) Hexacyanoferrate Films: Effect of the Supporting-Electrolyte Cation

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Abstract

Films of indium(III) hexacyanoferrate are studied in nitrate solutions of lithium, sodium, potassium, and ammonium using cyclic voltammetry and faradaic impedance. Effect of the supporting-electrolyte cation on parameters of the equivalent circuit corresponding to the impedance spectra is analyzed. The charge transport at the electrode/film interface is shown to be slow. The cation bonding in a film is discussed.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, Petrodvorets, St. Petersburg, 198504, Russia

    V. V. Kurdakova & V. V. Kondrat'ev

Authors
  1. V. V. Kurdakova
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  2. V. V. Kondrat'ev
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  3. V. V. Malev
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Kurdakova, V.V., Kondrat'ev, V.V. & Malev, V.V. Impedance of Indium(III) Hexacyanoferrate Films: Effect of the Supporting-Electrolyte Cation. Russian Journal of Electrochemistry 39, 878–883 (2003). https://doi.org/10.1023/A:1025164407951

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