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Electron Correlation Effects for Adiabatic Electrochemical Reactions of Electron Transfer in a Model for an Electrode with an Infinitely Wide Conduction Band: Diagrams of Kinetic Modes

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Abstract

For adiabatic electrochemical reactions, within the framework of a model for an electrode with an infinitely wide conduction band, exact results are obtained for critical regions that correspond to different possible types of electron transfer processes (transfer of a single electron with and without an intermediate state, simultaneous transfer of two electrons) and regions that correspond to electroadsorption of the reactant in certain charge states. These regions form a diagram of kinetic modes (DKM) in the space of model parameters. Analytical expressions for outermost curves of DKM are obtained for some extreme cases. For the general case of a model for an electrode with an infinitely wide conduction band, a DKM is constructed and investigated with exact allowance for the effects of electron–electron correlations.

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Authors and Affiliations

  1. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    A. M. Kuznetsov, I. G. Medvedev & V. V. Sokolov

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  1. A. M. Kuznetsov
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  2. I. G. Medvedev
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  3. V. V. Sokolov
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Kuznetsov, A.M., Medvedev, I.G. & Sokolov, V.V. Electron Correlation Effects for Adiabatic Electrochemical Reactions of Electron Transfer in a Model for an Electrode with an Infinitely Wide Conduction Band: Diagrams of Kinetic Modes. Russian Journal of Electrochemistry 39, 839–851 (2003). https://doi.org/10.1023/A:1025152005225

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  • DOI: https://doi.org/10.1023/A:1025152005225

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