Abstract
Kinetic stability of zinc complexes with meso-phenyltetrabenzoporphyrins in DMSO–HOAc mixture and in glacial acetic acid was studied. The stability of complexes was found to decrease with reduction in their macrocyclic effect and with increasing polarization of their macrocycles. The stability of nonplanar and nonsymmetrically substituted complexes was determined to be lower than that of the more planar and symmetrically substituted complexes.
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Berezin, D.B., Shukhto, O.V. & Galanin, N.E. Dissociation of Zinc Complexes in a Series of Phenyltetrabenzoporphyrins with Varying Macrocycle Rigidity. Russian Journal of Coordination Chemistry 29, 535–539 (2003). https://doi.org/10.1023/A:1025150018834
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DOI: https://doi.org/10.1023/A:1025150018834