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Influence of the Supporting Electrolyte Asymmetry on the Differential Capacitance Curves in a Model Description of Adsorption of Organic Cations at Electrode

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Abstract

Effect of supporting electrolyte asymmetry on the curves of differential capacitance of the electrical double layer during adsorption of organic cations at an electrode is considered within the Alekseev–Popov–Kolotyrkin model supplemented by a Frumkin isotherm. Taking into account the asymmetry substantially improves quantitative agreement between model calculations and experiment.

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References

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Authors and Affiliations

  1. Yaroslavl State Technical University, Yaroslavl, Russia

    S. I. Karpov

  2. Moscow State University, Vorob'evy Gory 1, Moscow, 119899, Russia

    B. B. Damaskin

Authors
  1. S. I. Karpov
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  2. B. B. Damaskin
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Karpov, S.I., Damaskin, B.B. Influence of the Supporting Electrolyte Asymmetry on the Differential Capacitance Curves in a Model Description of Adsorption of Organic Cations at Electrode. Russian Journal of Electrochemistry 39, 852–856 (2003). https://doi.org/10.1023/A:1025104122063

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  • DOI: https://doi.org/10.1023/A:1025104122063

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