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Soft template synthesis of macrocyclic copper(II) chelates with 3,9-dithio-4,8-diaza-6-oxaundekandithioamide-1,11 in a Cu2[Fe(CN)6]-gelatin-immobilized matrix

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Abstract

The complexing processes in the triple copper(II)–dithiomalonamide–methanal system taking place in the copper(II)hexacyanoferrate(II)-gelatin-immobilized matrix in contact with aqueous alkaline solutions (pH∼12), containing dithiomalonamide and methanal, have been studied. Template synthesis leading to a macrocyclic coordination compound with the tetradentate N,N,S,S-donor ligand, (3,9-dithio-4,8-diaza-6-oxaundekandithioamide-1,11), occurs under these specific conditions when dithiomalonamide and methanal are the ligand synthons.

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Authors and Affiliations

  1. Department of Analytical Chemistry, Kazan State Technological University, K. Marx Street 68, 420015, Kazan, Russia

    Oleg V. Mikhailov

  2. Department of Organic Chemistry, Kazan State University, Kremlin Street 18, 420008, Kazan, Russia

    Marina A. Kazymova, Tatyana A. Shumilova, Svetlana S. Solovieva & Tafkil G. Mannafov

Authors
  1. Oleg V. Mikhailov
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  2. Marina A. Kazymova
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  3. Tatyana A. Shumilova
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  4. Svetlana S. Solovieva
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  5. Tafkil G. Mannafov
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Mikhailov, O.V., Kazymova, M.A., Shumilova, T.A. et al. Soft template synthesis of macrocyclic copper(II) chelates with 3,9-dithio-4,8-diaza-6-oxaundekandithioamide-1,11 in a Cu2[Fe(CN)6]-gelatin-immobilized matrix. Transition Metal Chemistry 28, 592–594 (2003). https://doi.org/10.1023/A:1025038712436

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  • DOI: https://doi.org/10.1023/A:1025038712436

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