Skip to main content
Log in

Surfactants in Thin-Layer Chromatography

  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Data reported in the literature on the use of surfactants as modifiers of mobile and stationary phases in thin-layer chromatography are analyzed. The features of micellar and ion-pair versions of thin-layer chromatography and the dynamic and static modifications of stationary phases with surfactants are considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Farulla, E., Iacobelli-Turi, C., Lederer, M., and Salvetti, F., J. Chromatogr., 1963, vol. 12, p. 255.

    Google Scholar 

  2. Lepri, L., Desideri, P.G., and Heimler, D., J. Chromatogr., 1978, vol. 153, p. 77.

    Google Scholar 

  3. Lepri, L., Desideri, P.G., and Heimler, D., J. Chromatogr., 1978, vol. 155, p. 119.

    Google Scholar 

  4. Armstrong, D. and Terril, R.Q., Anal. Chem., 1979, vol. 51, no. 13, p. 2160.

    Google Scholar 

  5. Armstrong, D.W. and McNeely, M., Anal. Lett., 1979, vol. 12, p. 1285.

    Google Scholar 

  6. Armstrong, D.W., J. Liq. Chromatogr., 1980, vol. 3, no. 6, p. 895.

    Google Scholar 

  7. Armstrong, D.W., Solution Behavior of Surfactants, New York: Plenum, 1982, vol. 2, p. 1273.

    Google Scholar 

  8. Pelizzetti, E. and Pramauro, E., Anal. Chim. Acta, 1985, vol. 169, p. 1.

    Google Scholar 

  9. Berthod, A. and Dorsey, J.G., Analusis, 1988, vol. 16, no. 2, p. 75.

    Google Scholar 

  10. Van Petegheim, C. and Bijl, J., J. Chromatogr., 1981, vol. 210, no. 1, p. 113.

    Google Scholar 

  11. Hinze, W.L., Ann. Chim. (Rome), 1987, vol. 77, nos. 1-2, p. 167.

    Google Scholar 

  12. Medina Hernandez, M.J. and Garcia Alvarez-Coque, M.C., Analyst (London), 1992, vol. 117, no. 5, p. 831.

    Google Scholar 

  13. Shtykov, S.N., Sumina, E.G., Parshina, E.V., and Lopukhova, S.S., Zh. Anal. Khim., 1995, vol. 50, no. 7, p. 747.

    Google Scholar 

  14. Shtykov, S.N., Sumina, E.G., Smushkina, E.V., and Tyurina, N.V., J. Planar Chromatogr., 2000, vol. 13, no. 3, p. 182.

    Google Scholar 

  15. Savvin, S.B., Chernova, R.K., and Shtykov, S.N., Poverkhnostno-aktivnye veshchestva (Surfactants), Moscow: Nauka, 1991.

    Google Scholar 

  16. Pramauro, E. and Pelizzetti, E., Surfactants in Analytical Chemistry. Application of Organized Amphiphilic Media, Elsevier, 1996.

  17. Armstrong, D.W., Sep. Purif. Methods, 1985, vol. 14, p. 213.

    Google Scholar 

  18. Liu, H., Ling, J., and Yan, X., Zhejiang Gongxueyuan Xuebao, 1985, vol. 29, p. 39.

    Google Scholar 

  19. Hinze, W.L., in Ordered Media in Chemical Separations, Hinze, W.L. and Armstrong, D.W., Eds., ACS Symp. Series, no. 342, Washington, D.C.: Am. Chem. Soc., 1987, p. 2.

  20. Dorsey, J.G., Adv. Chromatogr., 1987, vol. 27, p. 167.

    Google Scholar 

  21. Khaledi, M.G., Trends Anal. Chem., 1988, vol. 7, p. 293.

    Google Scholar 

  22. Armstrong, D.W., Bui, K.H., and Barry, R.M., J. Chem. Educ., 1984, vol. 61, no. 5, p. 457.

    Google Scholar 

  23. Armstrong, D.W. and Nome, F., Anal. Chem., 1981, vol. 53, p. 1662.

    Google Scholar 

  24. Armstrong, D.W. and Stine, J.Y., J. Am. Chem. Soc., 1983, vol. 105, no. 10, p. 2962.

    Google Scholar 

  25. Shtykov, S.N., Zh. Anal. Khim., 2002, vol. 57, no. 10, p. 1018.

    Google Scholar 

  26. Rusanov, A.I., Mitselloobrazovanie v rastvorakh PAV (Micelle Formation in Solutions of Surfactants), St. Petersburg: Khimiya, 1992.

    Google Scholar 

  27. Armstrong, D.W. and Bui, K.H., J. Liq. Chromatogr., 1982, vol. 5, no. 6, p. 1043.

    Google Scholar 

  28. Sumina, E.G., Smushkina, E.V., Shtykov, S.N., and Tyurina, N.V., Zavod. Lab., 2001, vol. 67, no. 10, p. 13.

    Google Scholar 

  29. Armstrong, D.W., Hinze, W.L., Bui, K.H., and Singh, H.N., Anal. Lett., 1981, vol. 14, no. 19, p. 1659.

    Google Scholar 

  30. Weinberger, R., Yarmchuk, P., and Cline Love, L.J., Anal. Chem., 1982, vol. 54, no. 9, p. 1552.

    Google Scholar 

  31. Campiglia, A.D., Berthod, A., and Winefordner, J.D., J. Chromatogr., 1990, vol. 508, p. 37.

    Google Scholar 

  32. Alak, A., Heilweil, E., Hinze, W.L., Oh, H., and Armstrong, D.W., J. Liq. Chromatogr., 1984, vol. 7, p. 1273.

    Google Scholar 

  33. Hurtubise, R.J., Talanta, 1981, vol. 28, p. 145.

    Google Scholar 

  34. Sherma, J., Sleckman, B.P., and Armstrong, D.W., J. Liq. Chromatogr., 1983, vol. 6, no. 1, p. 95.

    Google Scholar 

  35. Shtykov, S.N., Sumina, E.G., Smushkina, E.V., and Tyurina, N.V., J. Planar Chromatogr., 1999, vol. 12, no. 2, p. 129.

    Google Scholar 

  36. Sumina, E.G., Smushkina, E.V., Shtykov, S.N., and Tyurina, N.V., Abstracts of Papers, Vserossiiskii simpozium po teorii i praktike khromatografii i elektroforeza (All-Russian Symp. on Theory and Practice of Chromatography and Electrophoresis), Samara, 1999, p. 170.

  37. Sumina, E.G., Shtykov S.N., and Tyurina, N.V., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, vol. 44, no. 4, p. 10.

    Google Scholar 

  38. Shtykov, S.N. and Sumina, E.G., Zh. Anal. Khim., 1998, vol. 53, no. 5, p. 508.

    Google Scholar 

  39. Shtykov, S.N., Sumina, E.G., and Tyurina, N.V., J. Planar Chromatogr., 2000, vol. 13, no. 4, p. 264.

    Google Scholar 

  40. Tabor, D.G. and Underwood, A.L., J. Chromatogr., 1989, vol. 463, no. 1, p. 73.

    Google Scholar 

  41. Mohammad, A. and Agrawal, V., J. Planar Chromatogr., 2000, vol. 13, no. 3, p. 210.

    Google Scholar 

  42. Sumina, E.G., Ermolaeva, E.V., Tyurina, N.V., and Shtykov, S.N., Zavod. Lab., 2001, vol. 67, no. 5, p. 5.

    Google Scholar 

  43. Mao, Z. and Zhang, Q., Fenxi Huaxue, 1984, vol. 12, no. 5, p. 455; cited by RZhKhim, 1984, 21G442.

    Google Scholar 

  44. Shtykov, S.N., Parshina, E.V., Sumina, E.G., Barabanova, I.V., and Malova, M.I, RF Patent 2038593, Byull. Izobret., 1995, no. 18.

  45. Sumina, E.G., Ufimtseva, I.N., and Lopukhova, S.S., Proc. 8th Russian–Japan Joint Symp. on Analytical Chemistry (RJSAC'96), Moscow, Saratov, 1996, p. 164.

    Google Scholar 

  46. Cai, Sh., Wu, Ch., and Mao, Zh., Zhejiang Yike Daxue Xuebao, 1988, vol. 17, p. 118.

    Google Scholar 

  47. Zhao, T., Su, Y., Chen, Y., Yang, Q., and Yu, R., Zhongguo Yaoke Daxue Xuebao, 1988, vol. 19, p. 82.

    Google Scholar 

  48. Lin, H., Ge, Z., Li, Zh., and Yu, R., Yaoxue Xuebao, 1991, vol. 26, p. 471.

    Google Scholar 

  49. Yin, P., Li, H., and Yan, Ch., Chin. J. Chromatogr., 1994, vol. 12, p. 35.

    Google Scholar 

  50. Ge, Z. and Lin, H., Fenxi Huaxue, 1992, vol. 20, p. 1369.

    Google Scholar 

  51. Mohammad, A., Tiwari, S., Chahar, J.P.S., and Kumar, S., J. Am. Oil Chem. Soc., 1995, vol. 72, p. 1533.

    Google Scholar 

  52. Mohammad, A. and Iraqi, E., J. Surfactants Deterg., 1999, vol. 2, p. 85.

    Google Scholar 

  53. Jain, R. and Gupta, S., J. Indian Chem. Soc., 1994, vol. 71, p. 709.

    Google Scholar 

  54. Zhao, T., Chin. J. Chromatogr., 1988, vol. 6, p. 209.

    Google Scholar 

  55. Sumina, E.G., Shtykov, S.N., and Tyurina, N.V., Zh. Fiz. Khim., 2002, vol. 76, no. 9, p. 1697.

    Google Scholar 

  56. Berthod, A., Girard, I., and Gonnet, C., Anal. Chem., 1986, vol. 58, p. 1356.

    Google Scholar 

  57. Berthod, A., Girard, I., and Gonnet, C., Anal. Chem., 1986, vol. 58, p. 1362.

    Google Scholar 

  58. Berthod, A. and Roussel, A., J. Chromatogr., 1988, vol. 449, p. 349.

    Google Scholar 

  59. Borgerding, M.F., Hinze, W.L., Stafford, L.D., Fulp, G.W., and Hamlin, W.C., Anal. Chem., 1989, vol. 61, p. 1353.

    Google Scholar 

  60. Dorsey, J.G., Khaledi, M.G., Landy, J.S., and Lin, J.L., J. Chromatogr., 1984, vol. 316, p. 183.

    Google Scholar 

  61. Mohammad, A. and Sirwal, Y.H., J. Planar Chromatogr., 2002, vol. 15, p. 107.

    Google Scholar 

  62. Armstrong, D.W. and Stine, J.Y., Anal. Chem., 1983, vol. 55, no. 14, p. 2317.

    Google Scholar 

  63. Shtykov, S.N., Sumina, E.G., and Tyurina, N.V., Zh. Anal. Khim., 2002, vol. 57, no. 4, p. 383.

    Google Scholar 

  64. Kord, A.S. and Khaledi, M.G., Anal. Chem., 1992, vol. 64, no. 17, p. 1901.

    Google Scholar 

  65. Szepesi, G., Vegh, Z., Gyulau, Z., and Gazdag, M., J. Chromatogr., 1984, vol. 290, p. 127.

    Google Scholar 

  66. Kovacz-Hadady, K. and Szilagyi, J., J. Chromatogr., 1991, vol. 553, nos. 1–2, p. 459.

    Google Scholar 

  67. Jain, R. and Bhatia, A., J. Indian Chem. Soc., 1990, vol. 67, no. 4, p. 355.

    Google Scholar 

  68. Pandey, P., Maheshwari, N., and Dave, A., J. Liq. Chromatogr., 1991, vol. 14, no. 18, p. 3311.

    Google Scholar 

  69. Lepri, L., Desideri, P.G., and Heimler, D., J. Chromatogr., 1981, vol. 209, no. 2, p. 312.

    Google Scholar 

  70. Wilson, I.D., J. Chromatogr., 1986, vol. 354, p. 99.

    Google Scholar 

  71. Lepri, L., Desideri, P.G., and Coas, V., J. Chromatogr., 1978, vol. 161, p. 279.

    Google Scholar 

  72. Lepri, L., Desideri, P.G., and Heimler, D., J. Chromatogr., 1979, vol. 169, p. 271.

    Google Scholar 

  73. Lepri, L., Desideri, P.G., and Heimler, D., J. Chromatogr., 1979, vol. 173, p. 119.

    Google Scholar 

  74. Lepri, L., Desideri, P.G., and Heimler, D., J. Chromatogr., 1980, vol. 195, p. 65.

    Google Scholar 

  75. Lepri, L., Desideri, P.G., and Heimler, D., J. Chromatogr., 1980, vol. 195, p. 187.

    Google Scholar 

  76. Lepri, L., Desideri, P.G., and Heimler, D., J. Chromatogr., 1981, vol. 207, p. 412.

    Google Scholar 

  77. Szepesi, G., Gazdag, M., Pap-Sziklay, Z., and Vegh, Z., Chromatographia, 1984, vol. 19, p. 422.

    Google Scholar 

  78. Sumina, E.G., Shtykov, S.N., Parshina, E.V., Tyurina, N.V., and Dorofeeva, S.V., in Problemy analiticheskoi khimii (Problems of Analytical Chemistry), Saratov: Saratovsk. Gos. Univ., 1999, p. 52.

    Google Scholar 

  79. Ling, B.L., Baeyens, W.K.G., Marysael, H., Stragier, K., and De Moerloose, P., J. Liq. Chromatogr., 1989, vol. 12, no. 16, p. 3135.

    Google Scholar 

  80. Grassini-Strazza, G., Carunchio, B., and Girelli, A.M., J. Chromatogr., 1989, vol. 466, p. 1.

    Google Scholar 

  81. Gazdag, M., Szepesi, G., Hernyes, M., and Vegh, Z., J. Chromatogr., 1984, vol. 290, p. 135.

    Google Scholar 

  82. Kovacs-Hadady, K. and Barna-Katona, K., J. Planar Chromatogr., 1989, vol. 2, p. 133.

    Google Scholar 

  83. Tomkinson, G.P., Wilson, I.D., and Ruane, R.J., J. Planar Chromatogr., 1989, vol. 2, p. 224.

    Google Scholar 

  84. Tesarova, E., Snopek, J., and Smolkova-Keulemansova, E., HRC & CC, J. High Resolut. Chromatogr. Chromatogr. Commun., 1987, vol. 10, p. 404.

    Google Scholar 

  85. Gonnet, C. and Marichy, M., Recent Develop. Chromatogr. Electrophoresis, 1980, vol. 10, p. 11.

    Google Scholar 

  86. Burton, S.J., McLoughlin, S.B., Stead, C.V., and Lowe, C.R., J. Chromatogr., 1988, vol. 435, no. 1, p. 127.

    Google Scholar 

  87. Lue, H. and Mo, J., Fenxi Huaxue, 1988, vol. 16, no. 9, p. 821.

    Google Scholar 

  88. Hauck, H.E. and Jost, W., Am. Lab., 1983, vol. 15, no. 8, p. 72.

    Google Scholar 

  89. Ahuja, S., Trace and Ultratrace Analysis by HPLC, New York: Wiley, 1992.

    Google Scholar 

  90. Jost, W. and Hauck, H.E., J. Chromatogr., 1983, vol. 264, p. 91.

    Google Scholar 

  91. Jost, W., Hauck, H.E., and Herbert, H., Chromatographia, 1984, vol. 18, p. 512.

    Google Scholar 

  92. Sumina, E.G., Shtykov, S.N., and Dorofeeva, S.V., Zh. Anal. Khim., 2002, vol. 57, no. 3, p. 257.

    Google Scholar 

  93. Troke, J.A. and Wilson, I.D., J. Chromatogr., 1986, vol. 360, p. 236.

    Google Scholar 

  94. Ruane, R.J., Wilson, I.D., and Troke, J.A., J. Chromatogr., 1986, vol. 368, p. 168.

    Google Scholar 

  95. Jost, W., Hauck, H.E., and Fischer, W., Chromatographia, 1987, vol. 21, p. 375.

    Google Scholar 

  96. Ojanpera, I. and Vuori, E., J. Liq. Chromatogr., 1987, vol. 10, p. 3595.

    Google Scholar 

  97. Junker-Buchheit, A. and Jork, H., J. Planar Chromatogr., 1988, vol. 1, p. 214.

    Google Scholar 

  98. Ruane, R.J. and Wilson, I.D., J. Chromatogr., 1988, vol. 441, p. 355.

    Google Scholar 

  99. Tomkinson, G.P., Wilson, I.D., and Ruane, R.J., J. Planar Chromatogr., 1990, vol. 3, p. 491.

    Google Scholar 

  100. Covacs-Hadady, K., J. Planar Chromatogr., 1996, vol. 9, p. 174.

    Google Scholar 

  101. Covacs-Hadady, K. and Varga, T., J. Planar Chromatogr., 1995, vol. 8, p. 292.

    Google Scholar 

  102. Covacs-Hadady, K., J. Planar Chromatogr., 1997, vol. 10, p. 18.

    Google Scholar 

  103. Lukacs, M., Barcsa, G., and Covacs-Hadady, K., J. Planar Chromatogr., 1997, vol. 10, p. 342.

    Google Scholar 

  104. Covacs-Hadady, K., Chromatographia, 1997, vol. 45, p. 81.

    Google Scholar 

  105. Torok, J. and Covacs-Hadady, K., J. Chromatogr., 1998, vol. 803, p. 235.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sumina, E.G., Shtykov, S.N. & Tyurina, N.V. Surfactants in Thin-Layer Chromatography. Journal of Analytical Chemistry 58, 720–730 (2003). https://doi.org/10.1023/A:1025027409149

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1025027409149

Keywords

Navigation