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Influence of the structure of amphiphilic anions on the Krafft temperature of micellar solutions of anionic surfactants

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Abstract

The influence of the structure of surfactants on the Krafft temperature T k was studied for aqueous solutions of anionic surfactants containing the sulfate and sulfonate head groups, the hydrophilic (H) and lipophilic (L) fragments in amphiphilic anions, and various polar and C8—C18 hydrocarbon groups. The best statistical quality was obtained for the model with separate account of the effect of the H and L structural fragments on the T k value.

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Bel'skii, V.E. Influence of the structure of amphiphilic anions on the Krafft temperature of micellar solutions of anionic surfactants. Russian Chemical Bulletin 52, 1347–1352 (2003). https://doi.org/10.1023/A:1024962710212

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