Skip to main content
Log in

Surface Phenomena and Interfacial Interaction at the Glass–Liquid Tin–Gas Phase Interface

  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

Abstract

We used the sessile drop method to study the temperature dependences of the density and surface tension of tin and liquid glass. We have studied the effect of the composition of the gas phase on the surface tension of the glass. We used the method of adjoining drops to determine the temperature dependence of the interfacial tension at the glass horbar; tin melt boundary. We have studied the effect of silicon, aluminum, iron, nickel, and manganese on the interfacial tension in the glass ― tin system. We have shown that in this system, these additives are not interface-active.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. V. N. Eremenko (ed.), Physical Chemistry of Inorganic Materials, Vol.3, Physical Chemistry of Reaction between Liquid Metals and Materials [in Russian], Nauk. Dumka, Kiev (1988).

    Google Scholar 

  2. Yu. M. Ivashchenko and V. N. Eremenko, Principles of Precision Measurement of Surface Energy of Melts by the Sessile Drop Method [in Ukrainian], Nauk. Dumka, Kiev (1972).

    Google Scholar 

  3. Yu. V. Naidich and V. N. Eremenko, “Large drop" method for determining surface tension and density of molten metals at high temperatures,” Fizika Metallov i Metallovedenie, 11, No. 6, 883–888 (1961).

    Google Scholar 

  4. V. I. Nizhenko and Yu. I. Smirnov, “Apparatus for determining surface properties and density of melts with semiautomatic delivery of samples to the heating zone,” in: Research Methods and Properties of Interfaces between Contacting Phases [in Russian], Nauk. Dumka, Kiev (1977), pp. 33–51.

    Google Scholar 

  5. V. I. Nizhenko, “Experimental estimate of the free surface energy of solids,” in: Surface Phenomena in Melts [in Russian], Nauk. Dumka, Kiev (1968), pp. 118–126.

    Google Scholar 

  6. V. I. Nizhenko and Yu. I. Smirnov, “Adjoining drop method for studying interfacial properties at the interface between two melts,” Adgeziya Rasplavov i Paika Materialov, No. 2, 6–9 (1977).

    Google Scholar 

  7. Yu. N. Ivashchenko, B. B. Bogatyrenko, and V. N. Eremenko, “Calculation of the surface tension of a liquid from sessile drop sizes,” in: Surface Phenomena in Melts and Powder Metallurgy Processes [in Russian], Izdat. Akad. Nauk Ukr. SSR, Kiev (1963), pp. 391–417.

    Google Scholar 

  8. Yu. V. Naidich, Contact Phenomena in Metallic Melts [in Russian], Nauk. Dumka, Kiev (1972).

    Google Scholar 

  9. S. I. Popel', V. V. Pavlov, V. N. Kozhurkov, and V. P. Nemchenko, “Some topics in theoretical and experimental study of surface phenomena,” in: Surface Phenomena in Melts [in Russian], Nauk. Dumka, Kiev (1977), pp. 125–163.

    Google Scholar 

  10. V. I. Nizhenko, “Density of liquid metals and its temperature dependence,” in: Research Methods and Properties of Interfaces between Contacting Phases [in Russian], Nauk. Dumka, Kiev (1968), pp. 86–105.

    Google Scholar 

  11. V. I. Nizhenko and L. I. Floka, Surface Tension of Liquid Metals and Alloys: Handbook [in Russian], Metallurgiya, Moscow (1981).

    Google Scholar 

  12. N. K. Adam, The Physics and Chemistry of Surfaces [Russian translation], Gostekhizdat, Moscow (1947).

    Google Scholar 

  13. V. V. Pavlov, S. I. Popel', and O. A. Esin, “Dependence of the interfacial tension on composition and temperature,” in: Surface Phenomena in Melts and Solid Phases Originating from Them [in Russian], Kabardino-Balkar. Kn. Izdat., Nal'chik (1965), pp. 136–141.

    Google Scholar 

  14. A. W. Adamson, Physical Chemistry of Surfaces [Russian translation], Mir, Moscow (1979).

    Google Scholar 

  15. V. E. Listovnichii and V. M. Sergeenkova, “Study of diffusion processes in a glass - liquid metal system,” in: The Physical Chemistry of Condensed Phases, Ultrahard Materials, and Their Interfaces [in Russian], Nauk. Dumka, Kiev (1975), pp. 209–218.

    Google Scholar 

  16. V. N. Eremenko, V. M. Sergienkova, V. E. Listovnichii, and O. V. Murzin, “Mass transport of tin from its melt to glass under an argon atmosphere with PO = 10- 16-10- 18 atm,” Dop. Akad. Nauk UkrRSR, Ser. A, No. 6, 560–564 (1975).

    Google Scholar 

  17. V. N. Eremenko, V. E. Listovnichii, and V. M. Sergienkova, “Mass transport of tin from its melt to glass in hydrogen medium,” Dop. Akad. Nauk UkrRSR, Ser. A, No. 7, 655–659 (1975).

    Google Scholar 

  18. V. N. Eremenko, V. M. Sergeenkova, and V. E. Listovnichii, “Contact interaction and mass transport in the tin melt - glass system,” in: The Physics of Interfacial Phenomena [in Russian], Izdat. Kabardino-Balkar. Univ., Nalchik (1976), pp. 94–106.

    Google Scholar 

  19. N. L. Pokrovskii and N. D. Galanina, “Properties of metallic solutions. IV. Surface tension of tin and tin- sodium melts,” Zhurn. Fiz. Khim., 23, No. 3, 324–331 (1949).

    Google Scholar 

  20. L. Goumiri and I. C. Joud, “Auger electron spectroscopy study of aluminium - tin liquid system,” Acta Metall., 30, No. 7, 1397–1405 (1982).

    Google Scholar 

  21. J. A. Champion, B. I. Keene, and J. M. Sillwood, “Wetting of aluminium oxide by molten aluminium and other metals,” J. Mater. Sci., 4, No. 1, 39–49 (1969).

    Google Scholar 

  22. R. D. Carnahan, T. L. Jonston, and C. H. Li, “Some observations of the wetting of Al2O3 by aluminium,” J. Amer. Ceram. Soc., 41, No. 9, 13–16 (1958).

    Google Scholar 

  23. O. A. Esin and P. V. Gel'd, The Physical Chemistry of Pyrometallurgical Processes [in Russian], Metallurgiya, Moscow (1966).

    Google Scholar 

  24. V. I. Nizhenko and Yu. I. Smirnov, “Temperature dependence of the density and surface tension of melts in the silicon - tin system,” Zhurn. Fiz. Khim., 68, No. 4, 752–754 (1994).

    Google Scholar 

  25. V. I. Nizhenko and Yu. I. Smirnov, “Temperature dependence of density and surface tension of melts in the aluminum - tin system,” Rasplavy, No. 1, 3–8 (1995).

    Google Scholar 

  26. V. I. Nizhenko and Yu. I. Smirnov, “Temperature dependence of the density and surface tension of binary melts of nickel and tin,” Izv. Akad. Nauk SSSR, Metally, No. 1, 29–32 (1994).

    Google Scholar 

  27. V. I. Nizhenko and L. I. Floka, “Density and surface properties of Fe - Sn melts,” Izv. Akad. Nauk SSSR, Metally, No. 4, 73–76 (1975).

    Google Scholar 

  28. V. I. Nizhenko and V. N. Eremenko, “Surface activity of additives in liquid metals,” Poroshk. Metall., No. 2, 11–18 (1964).

    Google Scholar 

  29. V. I. Nizhenko, “Using surface activity criteria to evaluate the reliability of surface tension data for binary metallic melts,” in: Adhesion and Contact Interaction of Melts [in Russian], Nauk. Dumka, Kiev (1988), pp. 3–17.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nizhenko, V.I. Surface Phenomena and Interfacial Interaction at the Glass–Liquid Tin–Gas Phase Interface. Powder Metallurgy and Metal Ceramics 42, 171–179 (2003). https://doi.org/10.1023/A:1024961916127

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1024961916127

Navigation