Skip to main content
SpringerLink
Log in

Structural Features of Grafted Phosphates in Mesopores of Si-MCM-41 and Ti,Si-MCM-41 Molecular Sieves

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

We have used 31P NMR (MAS) and IR spectroscopy and also chemical analysis to show that when Si- and Ti,Si-MCM-41 mesoporous molecular sieves are treated with phosphorus oxychloride, surface-anchored silicophosphate and titanophosphate compounds are formed of the type ≡(Si—O) x —{PO(OH)3−x } and ≡(Ti—O) x —{PO(OH)3−x } (x = 1, 2), and also compounds with the structure of titanium hydrophosphate and pyrophosphate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. C. T. Kresge, M. E. Leonowicz, W. J. Roth, et al., Nature, 359, 710-712 (1992).

    Google Scholar 

  2. A. S. Kovalenko, V. G. Il'in, and A. P. Filippov, Teor. Éksp. Khim., 36, No. 3, 322-337 (2000).

    Google Scholar 

  3. A. S. Kovalenko, A. S. Korchev, J. V. Chernenko, et al., Adsorpt. Sci. Technol., 17, No. 4, 245-254 (1999).

    Google Scholar 

  4. A. S. Kovalenko, A. S. Korchev, T. V. Koval'chuk, et al., Teor. Éksp. Khim., 38, No. 6, 370-376 (2002).

    Google Scholar 

  5. M. A. Alba, Z. Luan, and J. Klinowski, J. Phys. Chem., 100, No. 6, 2178-2182 (1996).

    Google Scholar 

  6. E. Astorino, J. B. Peri, R. J. Willey, and G. Busca, J. Catal., 157, No. 2, 482-500 (1995).

    Google Scholar 

  7. V. M. Mastikhin, I. L. Mudrakovsky, and A. V. Nosov, Progr. Nucl. Magn. Reson. Spectrosc., 23, 259-299 (1991).

    Google Scholar 

  8. V. M. Bogatyrev, V. V. Brei, and A. A. Chuiko, Teor. Éksp. Khim., 24, No. 5, 629-633 (1988).

    Google Scholar 

  9. K. I. Hadjiivanov, D. G. Klissurski, and A. A. Davydov, J. Catal., 116, No. 2, 498-505 (1989).

    Google Scholar 

  10. L. Mercier and T. J. Pinnavaia, Adv. Mater., 9, No. 6, 500-503 (1997).

    Google Scholar 

  11. S. B. Randarevich, V. V. Strelko, V. N. Belyakov, et al., Teor. Éksp. Khim., 24, No. 5, 633-636 (1988).

    Google Scholar 

  12. X. Helluy, C. Marichal, and A. Sebald, J. Phys. Chem. B., 104, No. 13, 2836-2845 (2000).

    Google Scholar 

  13. S. Roca and C. Airoldi, Thermochim. Acta, 284, 289-297 (1996).

    Google Scholar 

  14. A. S. Tarasevich, Ukr. Khim. Zh., 58, No. 3, 226-232 (1992).

    Google Scholar 

  15. A. Bhaumik and S. Inagaki, J. Am. Chem. Soc., 123, No. 4, 691-696 (2001).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Nauky Prospekt, 03028, Kyiv, Ukraine

    A. S. Kovalenko & V. G. Il'in

  2. Taras Shevchenko Kyiv National University, 60 Volodymyrs'ka Vul., 01033, Kyiv, Ukraine

    T. V. Koval'chuk & V. N. Zaitsev

Authors
  1. A. S. Kovalenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. V. Koval'chuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. N. Zaitsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. G. Il'in
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kovalenko, A.S., Koval'chuk, T.V., Zaitsev, V.N. et al. Structural Features of Grafted Phosphates in Mesopores of Si-MCM-41 and Ti,Si-MCM-41 Molecular Sieves. Theoretical and Experimental Chemistry 39, 195–200 (2003). https://doi.org/10.1023/A:1024945426509

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1024945426509

Search

Navigation