Abstract
Spectrophotometry was used to study charge-transfer complexes between substituted pyridine N-oxides and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone. Vertical ionization potentials of pyridine N-oxides in the gas phase and in solution were calculated by the CNDO/S3' method. The calculated ionization potentials in chloroform nicely correlate with the experimental charge-transfer wavelengths of the complexes.
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Shaforost, K.V., Semenov, S.G., Sverdlova, O.V. et al. Charge-Transfer Complexes between Substituted Pyridine N-Oxides and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone. Russian Journal of General Chemistry 73, 450–454 (2003). https://doi.org/10.1023/A:1024922306750
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DOI: https://doi.org/10.1023/A:1024922306750