Topics in Catalysis

, Volume 23, Issue 1–4, pp 191–198 | Cite as

Tracer Chromatographic Adsorption Studies in Relation to Liquid-Phase Catalysis

  • Dirk E. De Vos
  • Joeri Denayer
  • Frederik van Laar
  • Gino V. Baron
  • Pierre A. Jacobs
Article

Abstract

The hydrophobic or hydrophilic properties of solid catalysts often have a crucial influence on their properties in liquid-phase catalytic reactions. Several methods to measure liquid-phase adsorption on catalytic solids are compared, and special attention is given to the liquid chromatographic method. The experimental setup and the determination of adsorption constants are discussed. Finally, adsorption data measured via the chromatographic method are used to gain insight into liquid-phase catalytic reactions, particularly oxidations with Ti zeolites.

zeolites adsorption liquid chromatography 

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Copyright information

© Plenum Publishing Corporation 2003

Authors and Affiliations

  • Dirk E. De Vos
    • 1
  • Joeri Denayer
    • 2
  • Frederik van Laar
    • 1
  • Gino V. Baron
    • 2
  • Pierre A. Jacobs
    • 1
  1. 1.Centre for Surface Chemistry and CatalysisK.U. LeuvenLeuvenBelgium
  2. 2.Department of Chemical EngineeringVrije Universiteit BrusselBrusselBelgium

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