Abstract
Nitrogen oxide is an important gaseous air pollutant. It plays a major role in atmospheric chemistry, particularly in the formation of secondary air pollutants such as ozone, peroxyacyl nitrate (PAN), nitrate aerosols, and contributes to environmental acidification. A comprehensive assessment of NO2 levels in the atmosphere is required for developing effective strategies for control of air pollution and improvement of air quality. Consequently, spatial NO2 monitoring has become an important aspect of air quality assessment. Present NO2 monitoring networks are mostly confined to urban areas, having a limited number of monitoring sites. Wide spatial NO2 monitoring in India is constrained because of the limited availability of the monitoring equipment, such as continuous chemiluminesence monitors, high volume and handy samplers, which are expensive and need to be imported. Moreover, they require elaborate infrastructure, scientific personnel, technical support and uninterrupted power supply. In an effort to overcome the above shortcomings, passive samplers have been successfully used for large scale monitoring of NO2 in the ambient environment.
In recent years, passive samplers have been gaining increasing attention because they are simple, lightweight and cheap devices, which operate without any power source. Passive samplers have been found to be efficient, cost effective and free from the need for elaborate calibration and maintenance. Hence, they are ideally suited for developing a wide spatial network for NO2 monitoring. This paper presents a comprehensive review including, historical development and critical assessment of validation studies along with comparison of both badge and tube type passive samplers. An attempt has been also made to highlight advantages and limitations, as well as discussion on the factors affecting the efficiency of passive samplers under field conditions.
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Aoyama, T. and Yashiro, T.: 1983, 'Analytical Study of Low Concentration Gases, IV. Investigation of the Reaction by Trapping of Nitrogen Dioxide in Air Using the Triethanolamine Method,' Journal of Chromatography 256, 69-78.
Apling, A.J., Stevenson, K.J., Goldstein, B.D., Melia, R.J.W. and Atkins, D.H.F.: 1979, 'Air Pollution in Homes 2: Validation of Diffusion Tube Measurements,' Report LR 311 (AP), Warren Spring Laboratory, Stevenage, UK.
Ashenden, T.W. and Bell, S.A.: 1989, 'Rural Concentrations of Nitrogen Dioxide Pollution Throughout Wales,' Atmospheric Environment 58, 179-193.
Atkins, D.H.F. and Lee, D.S.: 1995, 'Spatial and Temporal Variation of Rural Nitrogen Dioxide Concentrations Across the United Kingdom,' Atmospheric Environment 29(2), 223-239.
Atkins, D.H.F., Sandalls, J., Law, D.V., Hough, A.M. and Stevenson, K.: 1986, 'The Measurement of Nitrogen Dioxide in the Outdoor Environment Using Passive Diffusion Tube Samplers,' United Kingdom Atomic Energy Authority Report, AERE R-12133, Harwell Laboratory, Oxfordshire.
Ayers, G.P., Keywood, M.D., Gillett, R., Manins, P.C., Malfroy, H. and Bardsley, T.: 1998, 'Validation of Passive Diffusion Samplers for SO2 and NO2,' Atmospheric Environment 32, 3587-3592.
Boleij, J.S.M., Lebret, E., Hoek, F., Noy, D. and Brunekreef, B.: 1986, 'The Use of Palmes Diffusion Tubes for Measuring NO2 in Homes,' Atmospheric Environment 20, 597-600.
Bower, J.S., Lampert, J.E., Stevenson, K.J., Atkins, D.H.F. and Law, D.V.: 1991, 'A Diffusion Tube Survey of NO2 Levels in Urban Areas of the U.K.,' Atmospheric Environment 25B(2), 255-265.
Bush, T., Mooney, D., Stevenson, K.: 1999, 'United Kingdom Nitrogen Dioxide Network, 1997,' AEA Technology, NETCEN, Culham, ISBN 0-7058-1774-1.
Bush, T., Smith, S., Stevenson, K. and Moorcroft, S.: 2001, 'Validation of Nitrogen Dioxide Diffusion Tube Methodology in the UK,' Atmospheric Environment 35, 289-296.
Cadoff, B.C. and Hodgeson, J.: 1983, 'Passive Sampler for Ambient Levels of Nitrogen Dioxide,' Analytical Chemistry 55, 2083-2085.
Campbell, G.W.: 1988, 'Measurements of Nitrogen Dioxide Concentrations at Rural Sites in the United Kingdom Using Diffusion Tubes,' Environmental Pollution 55, 251-270.
Campbell, G.W., Stedman, J.R. and Stevenson, K.: 1994, 'A Survey of Nitrogen Dioxide Concentrations in the United Kingdom Using Diffusion Tubes,' Atmospheric Environment 28, 477-486.
Colbeck, I.: 1998, 'Nitrogen Dioxide in the Workplace Environment', Environmental Monitoring and Assessment 52, 123-130.
EU: 1999, 'Council Directive 1999/30/EC Relating to Limit Values for Sulfur Dioxide, Nitrogen Dioxide and Oxides of Nitrogen, Particulate Matter and Lead in Ambient Air,' Official Journal of the European Communities L163/41.
Ferm, M. and Svanberg, P.A.: 1998, 'Cost-Efficient Technique for Urban and Background Measurement of SO2 and NO2,' Atmospheric Environment 32, 1377-1381.
Gair, A.J. and Penkett, S.A.: 1995, 'The Effects of Wind Speed and Turbulence on the Performance of Diffusion Tube Samplers,' Atmospheric Environment 29(18), 2529-2533.
Gair, A.J., Penkett, S.A. and Oyola, P.: 1991, 'Development of a Simple Passive Technique for the Determination of Nitrogen Dioxide in Remote Continental Locations,' Atmospheric Environment 25A, 1927-1939.
Girman, J.R. Hodgson, A.T., Robinson, B.K. and Traynor, G.W.: 1983, 'Laboratory Studies of the Temperature Dependence of the Palmes NO2 Passive Sampler,' Lawrence Berkeley Laboratory, University of California, Berkeley. Presented at the EPA National Symposium on Recent Advances in Pollutant Monitoring of Ambient Air and Stationary Sources, Raleigh, NC, May 3-6.
Glasius, M., Carlsen, M.F., Hansen, T.S. and Lohse, C.: 1999, 'Measurements of Nitrogen Dioxide on Funen Using Diffusion Tubes,' Atmospheric Environment 33, 1177-1185.
Gold, A.: 1977, 'Stoichiometry of Nitrogen Dioxide Determination in Triethanolamine Trapping Solution,' Analytical Chemistry 49, 1448-1450.
Hangertner, M., Burry, P. and Monn, C.: 1989, 'Passive Sampling of NO2, SO2 and O3 in Ambient Air,' in Proceedings of 8th World Clean Air Congress, Den Haag, The Netherlands.
Hansen, T.S., Kruse, M., Nissen, H., Glasius, M. and Lohse, C.: 2001, 'Measurements of Nitrogen Dioxide in Greenland Using Palmes Diffusion Tubes,' Journal of Environmental Monitoring 3, 139-145.
Hargreaves, K.J.: 1989, 'The Development and Application of Diffusion Tubes for Air Pollution Measurement,' Ph.D. Thesis, University of Nottingham.
Hargreaves, P.R., Leidi, A., Grubb, H.J., Howe, M.T. and Mugglestone, M.A.: 2000, 'Local and Seasonal Variations in Atmospheric Nitrogen Dioxide Levels at Rothamsted, UK, and Relationship with Meteorological Conditions,' Atmospheric Environment 34, 843-853.
Heal, M.R. and Cape, J.N.: 1997, 'A Numerical Evaluation of Chemical Interferences in the Measurement of Ambient Nitrogen Dioxide by Passive Diffusion Samplers,' Atmospheric Environment 31(13), 1911-1923.
Heal, M.R., O' Donoghue, M.A. and Cape, J.N.: 1999, 'Over estimation of Urban Nitrogen Dioxide by Passive Diffusion Tubes: A Comparative Exposures and Model Study,' Atmosphere Environment 33, 513-524.
Heal, M.R., Kirby, C. and Cape, J.N.: 2000, 'Systematic Biases in Measurement of Urban Nitrogen Dioxide Using Passive Diffusion Tube Samplers,' Environmental Monitoring and Assessment 62, 39-54.
Hewitt, C.N.: 1991, 'Spatial Variations in Nitrogen Dioxide Concentrations in an Urban Area,' Atmospheric Environment 25(3), 429-434.
Hisham, M.W.M. and Grosjean, D.: 1990, 'Sampling of Atmospheric Nitrogen Dioxide Using Triethanolamine: Interference from Peroxyacetyl Nitrate,' Atmospheric Environment 24A(9), 2523-2525.
Hoek, G., Meijer, R., Scholten, A., Noij, D. and Lebret, E.: 1984, 'The Relationship Between Indoor Nitrogen Dioxide Concentration Levels and Personal Exposure: A Pilot-Study,' International Archives Occupational Environmental Health 55, 73-78.
Kirby, C., Greig, A. and Drye, T.: 1998, 'Spatial and Temporal Variations in Nitrogen Dioxide Concentrations Across an Urban Landscape: Cambridge, UK,' Environmental Monitoring and Assessment 52, 65-82.
Kirby, C., Fox, M., Waterhouse, J. and Drye, T.: 2001, 'Influence of Environmental Parameters on the Accuracy of Nitrogen Dioxide Passive Diffusion Tubes for Ambient Measurement,' Journal of Environmental Monitoring 3, 150-158.
Kring, E.V., Lautenberger, W.J., Baker, W.B., Douglas, J.J. and Hoffman, R.A.: 1981, 'A New Passive Calorimetric Air Monitoring Badge System for Ammonia, Sulfur Dioxide and Nitrogen Dioxide,' American Industrial Hygiene Association Journal 42, 373-381.
Krochmal, D. and Gorski, L.: 1991b, 'Determination of Nitrogen Dioxide in Ambient Air by Use of a Passive Sampling Technique and Triethanolamine as Absorbent,' Environmental Science and Technology 25, 531-535.
Laxen, D.P.H. and Noordally, E.: 1987, 'NO2 Distribution in Street Canyons,' Atmospheric Environment 21, 1899-1903.
Lebret, E., Briggs, D., Reeuwijk, H.V., Fischer, P., Smallbone, K., Harssema, H., Kriz, B., Gorynski, P. and Elliott, P.: 2000, 'Small Area Variations in Ambient NO2 Concentrations in Four European Areas,' Atmospheric Environment 34, 177-185.
Levaggi, D.A., Wayman S., Feldstein, M. and Kothny, E.L.: 1972, 'Quantitative Separation of Nitric Oxide from Nitrogen Dioxide at Atmospheric Concentration Ranges,' Environmental Science and Technology 6, 250-252.
Moschandreas, D.J., Relwani, S.M. and Taylor, K.C.: 1990, 'A Laboratory Evaluation of Nitrogen Dioxide Personal Sampling Device,' Atmospheric Environment 24A(11), 2807-2811.
Motsumoto, M. and Mizoguchi, T.: 1988, 'A Simple Method for Simultaneous Measurement of Sulfur Dioxide and Nitrogen Dioxide in the Atmosphere by Triethanolamine Cylindrical Filter Method,' Chemical Abstract 109, 98000s.
Mulik, J., Lewis, R.G. and McCleany, W.A.: 1989, 'Modification of a High Efficiency Passive Sampler to Determine Nitrogen Dioxide or Formaldehyde in Air,' Analytical Chemistry 61, 187-189.
Noij, D., Lebret, E., Willers, H., Winkes, A., Boleij, J.S.M. and Brunekreef, B.: 1986, 'Estimating Human Exposures to Nitrogen Dioxide: Results from a Personal Monitoring Study Among Housewives,' Environment International 12, 407-411.
Noy, D., Lebret, E., Boleij, J.S.M. and Brunekreef, B.: 1984, 'Integrated NO2 Exposure Estimates,' in Indoor Air, Vol. 4, Chemical Characterisation and Personal Exposure, Swedish Council of Building Research, Stockholm, pp. 37-42.
Palmes, E.D., Gunnison, A.F., DiMattio, J. and Tomczyk, C.: 1976, 'Personal Sampler for Nitrogen Dioxide,' American Industrial Hygiene Association Journal 37, 570-577.
Palmes, E.D. and Johnson, E.R.: 1987, 'Explanation of Pressure Effects on a Nitrogen Dioxide Sampler,' American Industrial Hygiene Association Journal 48, 73-76.
Sickles, J.E., Grohse, P.M., Hodson, L.L., Salmons, C.A., Cox, K.W., Turner, A.R. and Estes, E.D.: 1990, 'Development of a Method for the Sampling and Analysis of Sulfur Dioxide and Nitrogen Dioxide from Ambient Air,' Analytical Chemistry 62, 338-346.
Spengler, J.D., Duffy, C.P., Letz, R., Tibbitts, T.W. and Ferris, B.G.J.R.: 1983, 'Nitrogen Dioxide Inside and Outside 137 Homes and Implications for Ambient air Quality Standards and Health Effects Research,' Environmental Science and Technology 17, 164-168.
Stevenson, K., Bush, T. and Mooney, D.: 2001, 'Five Years of Nitrogen Dioxide Measurement with Diffusion Tube Samplers at over 1000 Sites in the UK,' Atmospheric Environment 35, 281-287.
Van Reeuwijk, H., Fischer, P.H., Harssema, H., Briggs, D.J., Smallbone, K. and Lebret, E.: 1998, 'Field Comparison of Two NO2 Samplers to Assess Spatial Variation,' Environmental Monitoring and Assessment 50, 37-51.
Wilson, A.L.: 1987, 'Comparison of Passive and Chemiluminescence Monitors for Determining One-Week Average Nitrogen Dioxide Concentrations,' in Proceedings of Indoor Air Conference, Vol. 4, Berlin.
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Varshney, C., Singh, A.P. Passive Samplers for NOx Monitoring: A Critical Review. The Environmentalist 23, 127–136 (2003). https://doi.org/10.1023/A:1024883620408
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DOI: https://doi.org/10.1023/A:1024883620408