Abstract
Radical intermediates (phenyl and phenylcarbonyl radicals) formed in photooxidation of 4,4"-diazidodiphenyl in benzene and toluene have been studied by ESR spectroscopy. These radicals are formed as a result of abstraction of a hydrogen atom from a solvent molecule by the triplet nitrene—dioxygen complex.
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Zelentsov, S.V., Kuznetsov, M.V. & Zelentsova, N.V. ESR study of radical intermediates formed upon photooxidation of 4,4"-diazidodiphenyl. Russian Chemical Bulletin 52, 1296–1300 (2003). https://doi.org/10.1023/A:1024858623415
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DOI: https://doi.org/10.1023/A:1024858623415