Abstract
Phase conversions and kinetics of electrochemical intercalation of lithium from dimethylformamide solutions of LiCl into bulk electrodes of bismuth, indium and their intermetallic compounds InBi and In2Bi are studied using chronopotentiometry and chronoamperometry methods. The intercalation is controlled by non-steady-state lithium diffusion in the solid electrode. In the lithium–intermetallic compound systems, both components of alloys take part in the formation of compounds with lithium. Considerable volume changes, which occur during the intercalation, may lead to disintegration of lithium-containing phase constituents with a high lithium content. The “extremum” shape of cathodic chronoamperograms may be due successive and/or parallel reactions in which various lithium-containing compounds form. Some of these reactions are limited by solid-phase diffusion, while others involve the formation and diffusion-controlled growth of three-dimensional nuclei of a new phase.
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References
Skundin, A.M., Elektrokhim. Energ., 2001, vol. 1, p. 5.
Skundin, A.M., Efimov, O.N., and Yarmolenko, O.V., Usp. Khim., 2002, vol. 71, p. 378.
Besenhard, J.O., Yang, J., and Winter, M., J. Power Sources, 1997, vol. 68, p. 87.
Yang, J., Winter, M., and Besenhard, J.O., Solid State Ionics, 1996, vol. 90, p. 281.
Yang, J., Wachtler, M., Winter, M., and Besenhard, J.O., Electrochem. Solid-State Lett., 1999, vol. 2, p. 161.
Besenhard, J.O., Wachtler, M., Winter, M., Andreaus, R., Rom, I., and Sitte, W., J. Power Sources, 1999, vol. 81-82, p. 268.
Wishvender, K., Behl, T., and Edward, J., J. Power Sources, 1998, vol. 72, p. 132.
Narukawa, S., Amazutsumi, T., Fukuda, H., Itou, K., Tamaki, H., and Yamauchi, Y., J. Power Sources, 1998, vol. 76, p. 186.
Mao, O., Turner, R.L., Courtney, I.A., Fredericksen, B.D., Buckett, M.I., Krause, L.J., and Dahn, J.R., Electrochem. Solid-State Lett., 1999, vol. 2, p. 3.
Yang, J., Takeda, Y., Imanishi, N., Ichikawa, T., and Yamamoto, O., J. Power Sources, 1999, vol. 79, p. 220.
Thackeray, M.M., Vaughey, J.T., Kahaian, A.J., Kepler, K.D., and Benedek, R., Electrochem. Comm., 1999, p. 111.
Mao, O. and Dahn, J.R., J. Electrochem. Soc., 1999, vol. 146, p. 414.
Larcher, D., Beaulieu, L.Y., Mao, O., George, A.E., and Dahn, J.R., J. Electrochem. Soc., 2000, vol. 147, p. 1703.
Crosnier, O., Brousse, T., Devaux, X., Fragnaud, P., and Schleich, D.M., J. Power Sources, 2001, vol. 94, p. 169.
Vaughey, J.T., Johnson, C.S., Kropf, A.J., Benedek, R., Thackeray, M.M., Tostman, H., Sarakonsri, T., Hackney, S., Fransson, L., Edstrom, K., and Thomas, J.O., J. Power Sources, 2001, vol. 97-98, p. 194.
Benedek, R., Vaughey, J.T., Thackeray, M.M., Yang, L.H., and Prasad, R., J. Power Sources, 2001, vol. 97-98, p. 201.
Ozeryanskaya, V.V., Guterman, V.E., Shukaev, I.L., and Grigor'ev, V.P., Izv. Ross. Akad. Nauk, Ser. Khim., 1998, p. 1525.
Ozeryanskaya, V.V., Guterman, V.E., and Grigor'ev, V.P., Elektrokhimiya, 1999, vol. 35, p. 275.
Ozeryanskaya, V.V., Guterman, V.E., and Grigor'ev, V.P., Elektrokhimiya, 1999, vol. 35, p. 278.
Vol, A.E. and Kagan, I.K., Stroenie i svoistva dvoinykh metallicheskikh sistem (The Structure and Properties of Binary Metal Systems), Moscow: Nauka, 1976, vol. 3.
JCPDS, Philadelphia, 1995.
Guterman, V.E., Doctoral (Chem.) Dissertation, Rostovon-Don: Rostov. State Univ., 2001.
Knorre, D.G., Krylova, L.F., and Muzykantov, V.S., Fizicheskaya khimiya (Physical Chemistry), Moscow: Vysshaya Shkola, 1990.
Kabanov, B.N., Astakhov, I.I., and Kiseleva, I.G., Kinetika slozhnykh elektrokhimicheskikh reaktsii (The Kinetics of Complex Electrochemical Reactions), Moscow: Nauka, 1981, p. 200.
Ozeryanskaya, V.V., Guterman, V.E., and Grigor'ev, V.P., Elektrokhimiya, 1998, vol. 34, p. 755.
Marshakov, I.K., Vvedenskii, A.V., Kondrashin, V.Yu., and Bokov, G.A., Anodnoe rastvorenie i selektivnaya korroziya splavov (Anodic Dissolution and Selective Corrosion of Alloys), Voronezh: Voronezh. Gos. Univ., 1988.
Galus, Z., Fundamentals of Electrochemical Analysis, Chichester: Ellis Horwood, 1976.
Kiseleva, I.G., Tomashova, N.N., and Kabanov, B.N., Elektrokhimiya, 1983, vol. 19, p. 532.
Xianming, W., Nishina, T., and Uchida, I., J. Power Sources, 2001, vol. 452, p. 1.
Gamburg, Yu.D., Elektrokhimicheskaya kristallizatsiya metallov i splavov (Electrocrystallization of Metals and Alloys), Moscow: Yanus-K, 1997.
Kelaidopoulou, A., Kokkinidis, G., and Milchev, A., J. Electroanal. Chem., 1998, vol. 444, p. 195.
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Ozeryanskaya, V.V., Guterman, V.E. Electrochemical Intercalation of Lithium into Intermetallic Bismuth Compounds with Indium in Nonaqueous Solutions. Russian Journal of Electrochemistry 39, 784–792 (2003). https://doi.org/10.1023/A:1024838421636
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DOI: https://doi.org/10.1023/A:1024838421636