Abstract
The cobalt(ii) chloro complex with 1-allyltetrazole (Alltz) Co(Alltz)2Cl2 was studied by the magnetic susceptibility measurements and X-ray diffraction analysis. The coordination polyhedron of the complex is a distorted octahedron formed by the N(4) atoms of two Alltz cycles and four bridging Cl atoms (coordination unit CoN2Cl4). Each chlorine atom is bound with two cobalt atoms giving rise to a crimped polymeric network. The Co(Alltz)2Cl2 complex is a weak ferromagnetic with T N = 102±1 K and spontaneous magnetization σS(5 K) = 710±5 G cm3 mol–1. Hysteresis effects, depending on the intensity of the magnetic field in which the sample was cooled, were detected.
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L. G. Lavrenova, A. N. Bogatikov, L. A. Sheludyakova, V. N. Ikorskii, S. V. Larionov, and P. N. Gaponik, Zh. Neorg. Khim., 1991, 36, 1220 [J. Inorg. Chem. USSR, 1991, 36, 693 (Engl. Transl.)].
L. G. Lavrenova, V. N. Ikorskii, and S. V. Larionov, Zh. Neorg. Khim., 1993, 38, 1517 [J. Inorg. Chem. USSR, 1993, 38, 1416 (Engl. Transl.)].
L. G. Lavrenova, A. N. Bogatikov, V. N. Ikorskii, L. A. Sheludyakova, E. G. Boguslavskii, P. N. Gaponik, and S. V. Larionov, Zh. Neorg. Khim., 1996, 41, 423 [Russ. J. Inorg. Chem., 1996, 41, 406 (Engl. Transl.)].
A. V. Virovets, I. A. Baidina, V. I. Alekseev, N. V. Podberezskaya, and L. G. Lavrenova, Zh. Strukt. Khim., 1996, 37, 330 [Russ. J. Struct. Chem., 1996, 37, 288 (Engl. Transl.)].
A. V. Virovets, N. V. Podberezskaya, L. G. Lavrenova, and G. A. Bikzhanova, Acta Crystallogr., Sect. C., 1995, 51, 1084.
F. H. Allen and O. Kennard, Chemical Design Automatic News, 1993, 8, 31.
K. Waizumi, H. Masuda, H. Ohtaki, K. Tsukamoto, and I. Sunagawa, Bull. Chem. Soc. Jpn., 1990, 63, 3426.
Z. M. El Saffar, J. Phys. Soc. Jpn., 1962, 17, 1334.
A. E. Shvelashvili, E. V. Miminoshvili, V. K. Bel´skii, and T. O. Vardosanidze, Zh. Neorg. Khim., 1998, 43, 255 [Russ. J. Inorg. Chem., 1998, 43, 201 (Engl. Transl.)].
A. J. Kinneging, W. J. Vermin, and S. Gorter, Acta Crystallogr., Sect. B., 1982, 38, 1824.
G. Singh and D. B. Sowerby, J. Chem. Soc., Dalton Trans., 1977, 490.
C. Hemmert, M. Renz, H. Gornitzka, S. Soulet, and B. Meunier, Chem. Europ. J., 1999, 5, 1766.
B. Morosin, J. Chem. Phys., 1966, 44, 252.
R. Navarro and L. J. de Jongh, Physica, B, 1978, 94, 67.
D. B. Losee, J. N. McElearney, G. E. Shankle, and R. L. Carlin, Phys. Rev., B, 1973, 8, 2185.
U. Bossek, D. Nuhlen, E. Bill, T. Glaser, C. Krebs, T. Weyhermuller, K. Wieghardt, M. Lengen, and A. Trautwein, Inorg. Chem., 1997, 36, 2834.
T. Moriya, Phys. Rev., 1960, 120, 90.
I. F. Silvera, J. H. M. Thornley, and M. Tinkham, Phys. Rev., 1964, 136, A695.
V. I. Ovcharenko and R. Z. Sagdeev, Usp. Khim., 1999, 68, 381 [Russ. Chem. Rev., 1999, 68, 345 (Engl. Transl.)].
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Shvedenkov, Y.G., Virovets, A.V. & Lavrenova, L.G. Magnetic properties and crystal structure of the dichlorobis(1-allyltetrazole)cobalt(ii) complex. Russian Chemical Bulletin 52, 1353–1357 (2003). https://doi.org/10.1023/A:1024823027050
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DOI: https://doi.org/10.1023/A:1024823027050