Abstract
The results of positron annihilation experiments of solutions of n-hexanol in diols are compared to those of ultrasonic velocity and absorption. Variations of the annihilation parameters with composition allow the conclusion that the effect of hydrophobic solute on the original diol structure is limited. There are, however, significant similarities with the results known for aqueous systems, suggesting that clathrate-like solvates are forming in ethylene glycol, the phenomenon called here is a hydrophobic-like solvation. No evidences for it were found for the systems containing butanediols as solvents. Unfortunately, ultrasonic investigations do not confirm the formation of any specific structures, most possibly because the compressibilities of solvates are close to those of the pure components.
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See as an example: K. Jerie, A. Baranowski, B. Rozenfeld, B. Jeqowska-Trzebiatowska, J. Glirski, Acta Phys. Polon., A82 (1992) 183 and the papers cited therein.
H. S. Frank, M. W. Evans, J. Phys. Chem., 13 (1945) 507.
F. Franks, Ann. N. Y. Acad. Sci., 125 (1965) 277.
H. Endo, Bull. Chem. Soc. Japan, 16 (1973) 1586.
S. Ernst, W. Marczak, Bull. Acad. Polon. Sci. Chem., 40 (1992) 307.
S. Ernst, W. Marczak, G. Graczykowska, Acustica, 77 (1992) 86.
M. von Stackelberg, H. MÑller, Z. Elektrochem., 58 (1954) 25.
CRC Handbook of Chemistry and Physics, 56th ed., CRC Press, Cleveland, Ohio, USA, 1975.
S. Ernst, J. Glirski, B. Jeqowska-Trzebiatowska, Acta Phys. Polon., A64 (1979) 501.
K. Jerie, A. Baranowski, B. Rozenfeld, J. Glirski, S. Ernst, Phys. Scripta, 35 (1987) 729.
L. Pauling, in: The Nature of the Chemical Bond, 3rd ed., Cornell University Press, Ithaca-New York, 1960, p. 469.
H. S. Frank, A. S. Quist, J. Chem. Phys., 34 (1961) 604.
V. N. Yashkitshev, O. Ya. Samoilov, Zh. Strukt. Khim., 3 (1962) 211.
I. A. Chaban, M. N. Rodnikova, J. Barthel, L. L. Chaikov, S. V. Krivokhiza, V. V. Zhackova, J. Molec. Liq., 80 (1999) 27.
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Jerie, K., Baranowski, A., Gliński, J. et al. Hydrophobic-like solvation in non-aqueous solutions: Positron annihilation in and compressibility of n-hexanol in ethylene glycol, 1,2-butanediol and 1,4-butanediol. Journal of Radioanalytical and Nuclear Chemistry 257, 367–370 (2003). https://doi.org/10.1023/A:1024796115919
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DOI: https://doi.org/10.1023/A:1024796115919