Abstract
Using the method of Gibbs energy minimization, a computer-aided thermodynamic simulation of phase and chemical transformations in the MgO – C – Al – H2O – air system at 298 – 2400 K is carried out to describe the behavior of a carbonized periclase material with an Al-based antioxidizing additive. The effect of temperature and environmental atmosphere on phase and chemical transformations in the material bulk and material's pore space is studied. The properties of a carbon matrix doped with aluminum are discussed.
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Suvorov, S.A., Slobodov, A.A., Bocharov, S.V. et al. Thermodynamic Simulation of the Behavior of a Carbonized Periclase Refractory with an Aluminum-Based Antioxidant. Refractories and Industrial Ceramics 44, 103–107 (2003). https://doi.org/10.1023/A:1024719312067
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DOI: https://doi.org/10.1023/A:1024719312067